Issue 41, 2020

Direct C–H bond halogenation and pseudohalogenation of hydrocarbons mediated by high-valent 3d metal-oxo species

Abstract

Late-stage direct functionalization of the C–H bond is synthetically desirable. Metalloenzymes having metal-oxo active sites are well known to selectively catalyze hydroxylation and halogenation reactions with high efficiency. This review highlights the recent developments in the field of direct C–H halogenation and pseudohalogenation reactions catalyzed by the functional models of metalloenzymes.

Graphical abstract: Direct C–H bond halogenation and pseudohalogenation of hydrocarbons mediated by high-valent 3d metal-oxo species

Article information

Article type
Perspective
Submitted
18 Maw 2020
Accepted
18 Ndz 2020
First published
21 Ndz 2020

Dalton Trans., 2020,49, 14344-14360

Direct C–H bond halogenation and pseudohalogenation of hydrocarbons mediated by high-valent 3d metal-oxo species

N. Kannan, A. R. Patil and A. Sinha, Dalton Trans., 2020, 49, 14344 DOI: 10.1039/D0DT02533J

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