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Rhodamine derivatives (1–2) exhibited dual channel ‘turn-on’ photophysical signalling selectively with diethyl chlorophosphate (DCP) among various organophosphates (OPs), where the spiro-ring opening corresponds to the adduct formation through phosphorylation at their carbonyl O-spiro nucleophilic centres.

Graphical abstract: Selective DCP detection with xanthene derivatives by carbonyl phosphorylation

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