Improved malleability of miniemulsion-based vitrimers through in situ generation of carboxylate surfactants

Rinish Reddy Vaidyula; Pierre-Yves Dugas; Eleanor Rawstron; Elodie Bourgeat-Lami; Damien Montarnal

doi:10.1039/C9PY00644C

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Improved malleability of miniemulsion-based vitrimers through in situ generation of carboxylate surfactants†

Rinish Reddy Vaidyula,^a Pierre-Yves Dugas,

^a Eleanor Rawstron,^a Elodie Bourgeat-Lami

*^a and Damien Montarnal

*^a

Author affiliations

* Corresponding authors

^a Univ Lyon. Université Claude Bernard Lyon 1, CPE Lyon, CNRS, UMR 5265, Chemistry, Catalysis, Polymers and Processes, 43 Bvd du 11 Novembre 1918, F-69616 Villeurbanne, France
E-mail: damien.montarnal@univ-lyon1.fr, elodie.bourgeat-lami@univ-lyon1.fr

Abstract

Epoxy-acid vitrimer particles with excellent osmotic and hydrolytic stability were synthesized by miniemulsion polymerization thanks to in situ generation of surfactants from the carboxylic acid reagent and a water-soluble base. The sulfate-free vitrimers formed in this way show greatly reduced creep viscosities.

This article is part of the themed collection: Pioneering Investigators

Download options Please wait...

Supplementary files

Supplementary information PDF (456K)

Article information

DOI: https://doi.org/10.1039/C9PY00644C
Article type: Communication
Submitted: 02 Mud 2019
Accepted: 10 Mud 2019
First published: 13 Mud 2019

Download Citation

Polym. Chem., 2019,10, 3001-3005

Permissions

Request permissions

Improved malleability of miniemulsion-based vitrimers through in situ generation of carboxylate surfactants

R. R. Vaidyula, P. Dugas, E. Rawstron, E. Bourgeat-Lami and D. Montarnal, Polym. Chem., 2019, 10, 3001 DOI: 10.1039/C9PY00644C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Polymer Chemistry

Improved malleability of miniemulsion-based vitrimers through in situ generation of carboxylate surfactants†

Abstract

Supplementary files

Article information

Download Citation

Permissions

Improved malleability of miniemulsion-based vitrimers through in situ generation of carboxylate surfactants

Social activity

Search articles by author

Spotlight

Advertisements