Issue 39, 2019
From the journal:

Dalton Transactions

Palladium-mediated intramolecular dearomatization of ligated dialkylterphenyl phosphines†‡

Raquel J. Rama,a   Celia Mayab  and  M. Carmen Nicasio ORCID logo *a  

* Corresponding authors

a Departamento de Química Inorgánica, Universidad de Sevilla, Aptdo 1203, 41071 Sevilla, Spain
E-mail: mnicasio@us.es

b Instituto de Investigaciones Químicas (IIQ), Departamento de Química Inorgánica and Centro de Innovación en Química Avanzada (ORFEO-CINQA), Consejo Superior de Investigaciones Científicas (CSIC) and Universidad de Sevilla, Avda. Américo Vespucio 49, 41092 Sevilla, Spain

Abstract

Aryl–Pd(II) chlorides stabilized by dialkylterphenyl phosphine ligands undergo a thermal isomerization process, leading to the formation of allyl–Pd(II)-chloride species. The transformation involves the intramolecular functionalization of a C–H bond of the terphenyl group mediated by the Pd(II) center.

Graphical abstract: Palladium-mediated intramolecular dearomatization of ligated dialkylterphenyl phosphines

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Article information

DOI
https://doi.org/10.1039/C9DT03201K
Article type
Communication
Submitted
06 Mha 2019
Accepted
28 Mha 2019
First published
28 Mha 2019

Dalton Trans., 2019,48, 14575-14579

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Palladium-mediated intramolecular dearomatization of ligated dialkylterphenyl phosphines

R. J. Rama, C. Maya and M. C. Nicasio, Dalton Trans., 2019, 48, 14575 DOI: 10.1039/C9DT03201K

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