Chemically controlled crystal growth of (CH3NH3)2AgInBr6

Thao T. Tran; Michael A. Quintero; Kathryn E. Arpino; Zachary A. Kelly; Jessica R. Panella; Xiaoping Wang; Tyrel M. McQueen

doi:10.1039/C8CE00702K

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Chemically controlled crystal growth of (CH₃NH₃)₂AgInBr₆†

Thao T. Tran,

^a Michael A. Quintero,

‡^a Kathryn E. Arpino,

§^a Zachary A. Kelly,

^a Jessica R. Panella,

^a Xiaoping Wang

*^b and Tyrel M. McQueen

*^ac

Author affiliations

* Corresponding authors

^a Department of Chemistry, Department of Physics and Astronomy, Institute for Quantum Matter, Johns Hopkins University, Baltimore, MD 21218, USA
E-mail: mcqueen@jhu.edu

^b Neutron Scattering Division, Spallation Neutron Source, Oak Ridge National Laboratory, Oak Ridge, TN 39831, USA
E-mail: wangx@ornl.gov

^c Department of Materials Science and Engineering, Johns Hopkins University, Baltimore, MD 21218, USA

Abstract

We report the successful crystal growth of a previously unknown mixed-metal organic compound (CH₃NH₃)₂AgInBr₆. This phase, which is not obtained by direct combination of reactants, is crystallized through the use of Pb²⁺ (from CH₃NH₃PbBr₃) to modulate the soluble intermediates and force formation of (CH₃NH₃)₂AgInBr₆. Our results provide insights into mechanism and design-driven crystal growth and discovery of new halide materials that are chemically related to perovskites with photovoltaic and related applications.

This article is part of the themed collection: CrystEngComm New Talent

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Article information

DOI: https://doi.org/10.1039/C8CE00702K
Article type: Communication
Submitted: 30 Dzi 2018
Accepted: 13 Kho 2018
First published: 13 Kho 2018

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CrystEngComm, 2018,20, 5929-5934

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Chemically controlled crystal growth of (CH₃NH₃)₂AgInBr₆

T. T. Tran, M. A. Quintero, K. E. Arpino, Z. A. Kelly, J. R. Panella, X. Wang and T. M. McQueen, CrystEngComm, 2018, 20, 5929 DOI: 10.1039/C8CE00702K

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