Evidence of single electron transfer from the enolate anion of an N,N′-dialkyldiketopiperazine additive in BHAS coupling reactions

Katie J. Emery; Tell Tuttle; John A. Murphy

doi:10.1039/C7OB02209C

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Evidence of single electron transfer from the enolate anion of an N,N′-dialkyldiketopiperazine additive in BHAS coupling reactions†

Katie J. Emery,

^a Tell Tuttle

*^a and John A. Murphy

*^a

Author affiliations

* Corresponding authors

^a Department of Pure and Applied Chemistry, University of Strathclyde, 295 Cathedral Street, Glasgow G1 1XL, UK
E-mail: John.Murphy@strath.ac.uk, Tell.tuttle@strath.ac.uk

Abstract

A designed N,N′-dialkyldiketopiperazine (DKP) provides evidence for the role of DKP additives as initiators that act by electron transfer in base-induced homolytic aromatic substitution reactions, involving coupling of haloarenes to arenes.

This article is part of the themed collection: Mechanistic Aspects of Organic Synthesis

Download options Please wait...

Supplementary files

Supplementary information PDF (4683K)

Article information

DOI: https://doi.org/10.1039/C7OB02209C
Article type: Paper
Submitted: 02 Ndz 2017
Accepted: 05 Nhl 2017
First published: 05 Nhl 2017

Download Citation

Org. Biomol. Chem., 2017,15, 8810-8819

Permissions

Request permissions

Evidence of single electron transfer from the enolate anion of an N,N′-dialkyldiketopiperazine additive in BHAS coupling reactions

K. J. Emery, T. Tuttle and J. A. Murphy, Org. Biomol. Chem., 2017, 15, 8810 DOI: 10.1039/C7OB02209C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Organic & Biomolecular Chemistry

Evidence of single electron transfer from the enolate anion of an N,N′-dialkyldiketopiperazine additive in BHAS coupling reactions†

Abstract

Supplementary files

Article information

Download Citation

Permissions

Evidence of single electron transfer from the enolate anion of an N,N′-dialkyldiketopiperazine additive in BHAS coupling reactions

Social activity

Search articles by author

Spotlight

Advertisements