Issue 2, 2017

TTF–PTM dyads: from switched molecular self assembly in solution to radical conductors in solid state

Abstract

Organic donor–acceptor (D–A) systems formed by the electron-donor tetrathiafulvalene (TTF) linked to the electron-acceptor perchlorotriphenylmethyl (PTM) radical through different π-conjugated bridges exhibit interesting physical properties such as bistability in solution or conductivity in solid state. Understanding the interplay between intra- and intermolecular charge transfer processes in solution is of high interest in order to rationalize the self-assembling ability and conducting properties of such dyads in solid state. In this Highlight we examine the self-assembling properties of different TTF–π–PTM radical dyads that have potential applications as molecular switches or conductors in the field of molecular electronics.

Graphical abstract: TTF–PTM dyads: from switched molecular self assembly in solution to radical conductors in solid state

Article information

Article type
Highlight
Submitted
28 Maw 2016
Accepted
07 Ndz 2016
First published
14 Ndz 2016

CrystEngComm, 2017,19, 197-206

TTF–PTM dyads: from switched molecular self assembly in solution to radical conductors in solid state

M. Souto, C. Rovira, I. Ratera and J. Veciana, CrystEngComm, 2017, 19, 197 DOI: 10.1039/C6CE01660J

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