Issue 96, 2016

In situ spectroscopic characterization of a solution-phase X-type ligand exchange at colloidal lead sulphide quantum dot surfaces

Abstract

We employed quantitative NMR spectroscopy and spectrophotometric absorbance titration to study a quantum dot X-type ligand exchange reaction. We find that the exchange is highly cooperative, where at low extents of exchange the change in free energy of the reaction, ΔGXC, is ∼11 kJ mol−1 while at higher extents of exchange ΔGXC saturates to ∼−4 kJ mol−1. A modified Fowler binding isotherm is developed to describe the reaction.

Graphical abstract: In situ spectroscopic characterization of a solution-phase X-type ligand exchange at colloidal lead sulphide quantum dot surfaces

Supplementary files

Article information

Article type
Communication
Submitted
08 Nhl 2016
Accepted
07 Huk 2016
First published
07 Huk 2016

Chem. Commun., 2016,52, 13893-13896

In situ spectroscopic characterization of a solution-phase X-type ligand exchange at colloidal lead sulphide quantum dot surfaces

D. M. Kroupa, N. C. Anderson, C. V. Castaneda, A. J. Nozik and M. C. Beard, Chem. Commun., 2016, 52, 13893 DOI: 10.1039/C6CC08114B

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