Issue 75, 2016

Influence of step faceting on the enantiospecific decomposition of aspartic acid on chiral Cu surfaces vicinal to Cu{111}

Abstract

On surfaces vicinal to Cu{111}, L-aspartic acid (L-Asp) adsorption causes steps to facet enantiospecifically into {310}R and {320}S steps. L-Asp has its highest heat of adsortion on surfaces that naturally expose the {310}R or {320}S steps but decomposes preferentially on the {310}R steps.

Graphical abstract: Influence of step faceting on the enantiospecific decomposition of aspartic acid on chiral Cu surfaces vicinal to Cu{111}

Supplementary files

Article information

Article type
Communication
Submitted
19 Maw 2016
Accepted
18 Mha 2016
First published
18 Mha 2016

Chem. Commun., 2016,52, 11263-11266

Influence of step faceting on the enantiospecific decomposition of aspartic acid on chiral Cu surfaces vicinal to Cu{111}

A. D. Reinicker, A. J. Therrien, T. J. Lawton, R. Ali, E. C. H. Sykes and A. J. Gellman, Chem. Commun., 2016, 52, 11263 DOI: 10.1039/C6CC05957K

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