Issue 77, 2016
From the journal:

Chemical Communications

The role of counter-anions in the kinetics and chirality of porphyrin J-aggregates†

I. G. Occhiuto,ab   R. Zagami,c   M. Trapani,c   L. Bolzonello,b   A. Romeo,ac   M. A. Castriciano,*c   E. Collinib  and  L. Monsù Scolaro*ac  

* Corresponding authors

a Dipartimento di Scienze Chimiche, Biologiche, Farmaceutiche ad Ambientali, and C.I.R.C.M.S.B., University of Messina, V.le F. Stagno D'Alcontres 31, Vill. S. Agata, 98166 Messina, Italy
E-mail: lmonsu@unime.it

b Dipartimento di Scienze Chimiche, University of Padova, V. F. Marzolo 1 Padova, Italy

c CNR-ISMN, Istituto per lo Studio dei Materiali Nanostrutturati, c/o Dipartimento di Scienze Chimiche, Biologiche, Farmaceutiche ad Ambientali 98166, V.le F. Stagno D'Alcontres 31, Messina, Italy
E-mail: castriciano@pa.ismn.cnr.it

Abstract

Kinetics of the growth of TPPS4 porphyrin J-aggregates slow down in the order H2SO4 > HCl > HBr > HNO3 > HClO4, in agreement with the Hofmeister series. The rate constants and the extent of chirality correlate with the structure-making or breaking abilities of the different anions with respect to the hydrogen bonding network of the solvent.

Graphical abstract: The role of counter-anions in the kinetics and chirality of porphyrin J-aggregates

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Article information

DOI
https://doi.org/10.1039/C6CC05768C
Article type
Communication
Submitted
13 Maw 2016
Accepted
24 Mha 2016
First published
25 Mha 2016

Chem. Commun., 2016,52, 11520-11523

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The role of counter-anions in the kinetics and chirality of porphyrin J-aggregates

I. G. Occhiuto, R. Zagami, M. Trapani, L. Bolzonello, A. Romeo, M. A. Castriciano, E. Collini and L. Monsù Scolaro, Chem. Commun., 2016, 52, 11520 DOI: 10.1039/C6CC05768C

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