Issue 55, 2016

Ship in a breakable bottle: fluoride-induced release of an organic molecule from a Pr(iii)-linked molecular cage

Abstract

A 3-dimensional networked molecular cage, NMC-1, has been synthesized. This macrocycle-based framework was prepared from a solvothermal reaction involving a flexible organic building block, calix[4]pyrrole dibenzoic acid (H2L), and Pr(NO3)3·6H2O. A unique feature of NMC-1 is that it retains free calix[4]pyrrole molecules in the framework pores. Treatment with a fluoride anion source serves to destroy the network and allows release of the organic guest. The net result is a ‘molecular ship’ in a ‘breakable bottle’.

Graphical abstract: Ship in a breakable bottle: fluoride-induced release of an organic molecule from a Pr(iii)-linked molecular cage

Supplementary files

Article information

Article type
Communication
Submitted
26 Dzi 2016
Accepted
25 Mud 2016
First published
27 Mud 2016

Chem. Commun., 2016,52, 8514-8517

Ship in a breakable bottle: fluoride-induced release of an organic molecule from a Pr(III)-linked molecular cage

J. Lee, N. W. Waggoner, L. Polanco, G. R. You, V. M. Lynch, S. K. Kim, S. M. Humphrey and J. L. Sessler, Chem. Commun., 2016, 52, 8514 DOI: 10.1039/C6CC03471C

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