Issue 14, 2016

Moving systems of polar dimeric capsules out of thermal equilibrium by light irradiation

Abstract

Heterodimeric capsules self-assembled from tetraurea calix[4]pyrrole and tetraurea calix[4]arene provide unique molecular containers for the organised inclusion of small polar molecules. By inserting stimuli-responsive groups (azobenzene) in the heterocapsule structure, we are able to modify the equilibrium state of the system or the exchange between different host–guest assemblies in a reversible manner.

Graphical abstract: Moving systems of polar dimeric capsules out of thermal equilibrium by light irradiation

Supplementary files

Article information

Article type
Communication
Submitted
18 N’w 2015
Accepted
12 Sun 2016
First published
12 Sun 2016

Chem. Commun., 2016,52, 3046-3049

Author version available

Moving systems of polar dimeric capsules out of thermal equilibrium by light irradiation

A. Díaz-Moscoso, F. A. Arroyave and P. Ballester, Chem. Commun., 2016, 52, 3046 DOI: 10.1039/C5CC10403C

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