Issue 92, 2014

Polaron stability in semiconducting polymer neat films

Abstract

We describe a spectroelectrochemical approach to accelerated electrochemical stability studies of conjugated polymers under oxidative stress. The polaron stabilities of alternating copolymers based on (i) thiophene and thiazole, namely PTTz, and (ii) bithiophene and thiazole, namely PTTTz, are compared in neat films with that of P3HT. P3HT is found to be the most stable whilst PTTz is found to be the least stable.

Graphical abstract: Polaron stability in semiconducting polymer neat films

Supplementary files

Article information

Article type
Communication
Submitted
07 Mha 2014
Accepted
25 Ndz 2014
First published
26 Ndz 2014

Chem. Commun., 2014,50, 14425-14428

Polaron stability in semiconducting polymer neat films

D. Beatrup, J. Wade, L. Biniek, H. Bronstein, M. Hurhangee, J. Kim, I. McCulloch and J. R. Durrant, Chem. Commun., 2014, 50, 14425 DOI: 10.1039/C4CC06193D

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