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Abstract | Cited by

A fluorous organocatalyst promotes direct asymmetric aldol reactions of aromatic aldehydes with ketones in brine to afford the corresponding anti-aldol products in high yield with up to 96% ee. Fluorous organocatalyst can be readily recovered by solid phase extraction using fluorous silica gel and reused without purification.

Graphical abstract: Highly efficient asymmetric aldol reaction in brine using a fluorous sulfonamide organocatalyst

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