Issue 14, 2012

Influence of ligand field stabilization energy on the elastic properties of multiferroic MOFs with the perovskite architecture

Abstract

We report the mechanical properties of four isostructural metal–organic frameworks (MOFs) that adopt the ABX3 perovskite topology: [(CH3)2NH2]M(HCOO)3, where M = divalent Mn, Co, Ni, and Zn. Their Young's moduli were measured via single-crystal nanoindentation. We show that the mechanical stability of such isostructural frameworks with octahedral coordination increases with greater ligand field stabilization energy (LFSE).

Graphical abstract: Influence of ligand field stabilization energy on the elastic properties of multiferroic MOFs with the perovskite architecture

Supplementary files

Article information

Article type
Communication
Submitted
30 Huk 2011
Accepted
08 Sun 2012
First published
02 Yan 2012

Dalton Trans., 2012,41, 3949-3952

Influence of ligand field stabilization energy on the elastic properties of multiferroic MOFs with the perovskite architecture

J. Tan, P. Jain and A. K. Cheetham, Dalton Trans., 2012, 41, 3949 DOI: 10.1039/C2DT12300B

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