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A facile in situ nanoparticle seeding method is reported to prepare MIL-101(Cr) films on alumina supports. The in situ seeding of MIL-101(Cr) nanoparticles was promoted by use of dimethylacetamide (DMA). The generality of this approach is further demonstrated for Cu3(btc)2 films by using a (poly)acrylate promoter.

Graphical abstract: Facile synthesis of metal–organic framework films via in situ seeding of nanoparticles

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