Issue 19, 2012

Contrasting reductions of group 14 metal(ii) chloride complexes: synthesis of a β-diketiminato tin(i) dimer

Abstract

Reductions of the β-diketiminato group 14 metal(II) chloride complexes, [(ButMesNacnac)ECl] (ButMesNacnac = [(MesNCBut)2CH]; Mes = mesityl; E = Ge, Sn or Pb), with a magnesium(I) dimer have led to differing outcomes, which include the formation of the first β-diketiminato group 14 metal(I) dimer, [{(ButMesNacnac)Sn}2].

Graphical abstract: Contrasting reductions of group 14 metal(ii) chloride complexes: synthesis of a β-diketiminato tin(i) dimer

Supplementary files

Article information

Article type
Communication
Submitted
26 N’w 2011
Accepted
08 Sun 2012
First published
10 Sun 2012

Chem. Commun., 2012,48, 2504-2506

Contrasting reductions of group 14 metal(II) chloride complexes: synthesis of a β-diketiminato tin(I) dimer

S. L. Choong, C. Schenk, A. Stasch, D. Dange and C. Jones, Chem. Commun., 2012, 48, 2504 DOI: 10.1039/C2CC18086C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements