Issue 20, 2012
From the journal:

Chemical Communications

The high yielding synthesis of pillar[5]arenes under Friedel–Crafts conditions explained by dynamic covalent bond formation†‡

Michel Holler,a   Nicolas Allenbach,a   Jordan Soneta  and  Jean-François Nierengarten*a  

* Corresponding authors

a Laboratoire de Chimie des Matériaux Moléculaires, Université de Strasbourg et CNRS, Ecole Européenne de Chimie, Polymères et Matériaux, 25 rue Becquerel, 67087 Strasbourg Cedex 2, France
E-mail: nierengarten@unistra.fr

Abstract

Systematic investigations of the cyclooligomerization of 1,4-disubstituted hydroquinone derivatives under Friedel–Crafts conditions have been carried out to demonstrate that the formation of pillar[5]arenes occurs under thermodynamic control.

Graphical abstract: The high yielding synthesis of pillar[5]arenes under Friedel–Crafts conditions explained by dynamic covalent bond formation

  • This article is part of the themed collection: Aromaticity
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Article information

DOI
https://doi.org/10.1039/C2CC16795F
Article type
Communication
Submitted
02 Huk 2011
Accepted
01 N’w 2011
First published
02 N’w 2011

Chem. Commun., 2012,48, 2576-2578

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The high yielding synthesis of pillar[5]arenes under Friedel–Crafts conditions explained by dynamic covalent bond formation

M. Holler, N. Allenbach, J. Sonet and J. Nierengarten, Chem. Commun., 2012, 48, 2576 DOI: 10.1039/C2CC16795F

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