Issue 6, 2009

Structural and chemical complexity in multicomponent inorganic–organic framework materials

Abstract

A family of coordination polymers with remarkable structural and chemical complexity is produced when Cu and Zn are combined with 5-hydroxyisophthalic acid and 4,4′-bipyridyl. The structures of these four- and five-component phases are fully ordered, with the two metals occupying different sites and the ligands playing distinct bridging roles in each structure. In one five-component phase, oxalate forms as a product of partial ligand decomposition and is incorporated alongside the two original ligands into the resultant solid. The valence of Cu and the Cu/Zn ratios differ between the phases, in spite of similar synthetic conditions.

Graphical abstract: Structural and chemical complexity in multicomponent inorganic–organic framework materials

Supplementary files

Article information

Article type
Communication
Submitted
19 Huk 2008
Accepted
06 Sun 2009
First published
10 Yan 2009

CrystEngComm, 2009,11, 980-985

Structural and chemical complexity in multicomponent inorganic–organic framework materials

R. K. Feller and A. K. Cheetham, CrystEngComm, 2009, 11, 980 DOI: 10.1039/B820718F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements