Issue 11, 2008
From the journal:

Chemical Communications

Anion induced and inhibited circumrotation of a [2]catenane†

Ka-Yuen Ng,a   Vitor Felix,b   Sérgio M. Santos,b   Nicholas H. Reesa  and  Paul D. Beer*a  

* Corresponding authors

a Inorganic Chemistry Laboratory, Department of Chemistry, University of Oxford, South Parks Road, Oxford, UK
E-mail: paul.beer@chem.ox.ac.uk
Fax: +44 (0)1865-272690
Tel: +44 (0)1865-285142

b Departamento de Química, CICECO e Escola Superior de Saúde, Universidade de Aveiro, Aveiro, Portugal
E-mail: vitor.felix@ua.pt
Fax: +351 234-370084
Tel: +351 234-370729

Abstract

The first example of a catenane capable of performing circumrotation via an anion switching methodology is described; of particular interest is a conformational locking mechanism which results from chloride coordination in the catenane binding cavity.

Graphical abstract: Anion induced and inhibited circumrotation of a [2]catenane

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Article information

DOI
https://doi.org/10.1039/B719304A
Article type
Communication
Submitted
16 N’w 2007
Accepted
09 Sun 2008
First published
30 Sun 2008

Chem. Commun., 2008, 1281-1283

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Anion induced and inhibited circumrotation of a [2]catenane

K. Ng, V. Felix, S. M. Santos, N. H. Rees and P. D. Beer, Chem. Commun., 2008, 1281 DOI: 10.1039/B719304A

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