Issue 3, 2006
From the journal:

CrystEngComm

Solvent-free synthesis of a microporous metal–organic framework†

Anne Pichon,a   Ana Lazuen-Garaya  and  Stuart L. James*a  

* Corresponding authors

a Centre for the Theory and Application of Catalysis, School of Chemistry and Chemical Engineering, Queen's University Belfast, David Keir Building, Stranmillis Road, Belfast, UK
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Tel: +44 (0)28 90975419

Abstract

We describe the first solvent-free mechanochemical synthesis of a microporous metal–organic framework [Cu(INA)2] (INA = isonicotinic acid); the product has robust 3-dimensional connectivity and is obtained quantitatively by grinding together copper acetate and isonicotinic acid for 10 minutes without any applied heating—the high efficiency of the synthesis suggests that mechanochemical synthesis should be further investigated as a convenient method for the preparation of microporous metal–organic frameworks (MOFs).

Graphical abstract: Solvent-free synthesis of a microporous metal–organic framework

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Article information

DOI
https://doi.org/10.1039/B513750K
Article type
Communication
Submitted
28 Ndz 2005
Accepted
25 Sun 2006
First published
06 Yan 2006

CrystEngComm, 2006,8, 211-214

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Solvent-free synthesis of a microporous metal–organic framework

A. Pichon, A. Lazuen-Garay and S. L. James, CrystEngComm, 2006, 8, 211 DOI: 10.1039/B513750K

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