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Nanoscale

Controllable syntheses of two structurally new {AsW9O33}-mediated silver alkynyl clusters

Qingqing Liu,a   Yeqin Feng,a   Tianfu Liu, ORCID logo *a   Mengyun Zhao,a   Yurui Li,a   Hongjin Lv ORCID logo *a  and  Guo-Yu Yang ORCID logo a  

* Corresponding authors

a MOE Key Laboratory of Cluster Science, Beijing Key Laboratory of Photoelectric/Electrophotonic Conversion Materials, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 102488, P. R. China
E-mail: liutf@bit.edu.cn, hlv@bit.edu.cn

Abstract

In this work, two structurally new silver alkynyl clusters, [(AsW9O33)2@Ag48(NO3)6(tBuC[triple bond, length as m-dash]C)24(DMF)6]·3CH3CN (1) and [(AsW9O33)2@Ag56(NO3)4Cl2(tBuC[triple bond, length as m-dash]C)32]n (2), were successfully synthesized using the trilacunary B-α-[AsW9O33]9− as an anionic template via a facile one-pot solvothermal approach. The molecular structures of clusters 1 and 2 can be controlled using different mixed reaction solvents. Compounds 1 and 2 also demonstrate efficient photothermal conversion properties and notable catalytic activities towards the detoxification of 4-nitrophenol.

Graphical abstract: Controllable syntheses of two structurally new {AsW9O33}-mediated silver alkynyl clusters

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Article information

DOI
https://doi.org/10.1039/D5NR03313F
Article type
Communication
Submitted
05 Aug 2025
Accepted
29 Aug 2025
First published
29 Aug 2025

Nanoscale, 2025, Advance Article

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Controllable syntheses of two structurally new {AsW9O33}-mediated silver alkynyl clusters

Q. Liu, Y. Feng, T. Liu, M. Zhao, Y. Li, H. Lv and G. Yang, Nanoscale, 2025, Advance Article , DOI: 10.1039/D5NR03313F

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