Bio-derived chitosan additive enables anion anchoring and Zn(002) deposition for high-performance Zn anodes†
Abstract
Bio-derived quaternary-ammonium-functionalized chitosan (HACC) was investigated as an electrolyte additive for Zn anode stabilization, for the first time to the best of our knowledge. Due to its special structure, including abundant hydrophilic functional groups and positive charge, HACC can inhibit the hydrogen evolution reaction, promote Zn2+ transport, and induce the deposition of Zn(002). Consequently, the electrolyte with HACC exhibits improved electrochemical performance.
- This article is part of the themed collection: Chemistry at the Forefront of the Sustainable Energy Transition