Issue 73, 2024

An extended-gate-type organic transistor for monitoring the Menschutkin reaction of tetrazole at a solid–liquid interface

Abstract

We herein propose an approach to visualize the Menschutkin reaction at an interface between a self-assembled monolayer with nucleophilic properties and water containing alkyl halides. An organic field-effect transistor functionalized with a nucleophilic monolayer has detected in situ alkylation depending on differences in the leaving group ability and the bulkiness of electrophilic alkyls.

Graphical abstract: An extended-gate-type organic transistor for monitoring the Menschutkin reaction of tetrazole at a solid–liquid interface

Supplementary files

Article information

Article type
Communication
Submitted
01 Maw 2024
Accepted
12 Mha 2024
First published
13 Mha 2024

Chem. Commun., 2024,60, 9930-9933

An extended-gate-type organic transistor for monitoring the Menschutkin reaction of tetrazole at a solid–liquid interface

Y. Sasaki, K. Ohshiro, X. Lyu, T. Kawashima, M. Kamiko, H. Tanaka, A. Yamagami, Y. Ueno and T. Minami, Chem. Commun., 2024, 60, 9930 DOI: 10.1039/D4CC03266G

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