Issue 14, 2023

Alkali metal carbonate catalyzed copolymerization of anhydrides and epoxides: a simple, efficient and versatile approach to well-defined alternating polyesters

Abstract

Ring-opening alternating copolymerization (ROAC) has recently become an attractive strategy for polyester synthesis. To date, ROAC catalysts have been restricted to organometallics and organic super-bases. In this work, we report ROAC using alkali metal carbonates (AMCs), one of the most common, simple, and inexpensive reagents in the laboratory, as efficient and environmentally benign catalysts. The ROAC of phthalate anhydride (PA) and propylene oxide (PO) can be catalyzed efficiently by AMC at 100 °C to afford polyesters with perfectly alternating structures. The structural and functional diversity of the resultant polyesters can be expanded by using various epoxide monomers and alcohol initiators. An alkali metal cation dissociated from the AMC successively activates the anhydride and the epoxide, and the carbonate anion activates the terminated hydroxyl. The cooperative catalysis accelerates the generation of the alternating structure.

Graphical abstract: Alkali metal carbonate catalyzed copolymerization of anhydrides and epoxides: a simple, efficient and versatile approach to well-defined alternating polyesters

Supplementary files

Article information

Article type
Paper
Submitted
30 Huk 2022
Accepted
08 Kul 2023
First published
09 Kul 2023

Polym. Chem., 2023,14, 1630-1638

Alkali metal carbonate catalyzed copolymerization of anhydrides and epoxides: a simple, efficient and versatile approach to well-defined alternating polyesters

H. Xie, L. Zheng, J. Feng, X. Wang, S. Kuang, L. Zhou, J. Jiang, Y. Xu, Y. Zhao and Z. Xu, Polym. Chem., 2023, 14, 1630 DOI: 10.1039/D2PY01507B

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