Bo Li, Pengfei Xue, Yu Bai, Qin Tang, Man Qiao and Dongdong Zhu
Chem. Commun., 2023,59, 5086-5089
DOI:
10.1039/D3CC00864A,
Communication
Electrochemical conversion of nitrate to NH3 not only eliminates nitrate pollution in the environment, but also produces highly valuable NH3. Herein, Cu-doped Co3O4 with abundant oxygen vacancies (Cu–Co3O4−x) was prepared on carbon cloth. The as-fabricated Cu–Co3O4−x can selectively reduce nitrate to NH3 with high Faraday efficiencies (around 90%) and a large NH3 yield of 0.83 mmol h−1 cm−2 in a neutral electrolyte.