Issue 12, 2021

Cooperativity in supported metal single atom catalysis

Abstract

The discussion concerning cooperativity in supported single-atom (SA) catalysis is often limited to the metal–support interaction, which is certainly important, but which is not the only lever for modifying the catalytic performance. Indeed, if the interaction between the SA and the support, which can be seen as a solid ligand presenting its own specificities that fix the first coordination sphere of the metal, plays a central role as in homogeneous catalysis, other factors can strongly contribute to modification of the activity, selectivity and stability of SAs. Therefore, in this mini-review, we briefly summarize the importance of the support (oxide, carbon or a second metal) in SA photo- electro- and thermal-catalysis (support-assisted operation), and concentrate on other types of cooperativities that in some cases enable previously impossible reaction pathways on supported metal SAs. This includes topics that are not specific to SA catalysis, such as metal–ligand or heterobimetallic cooperativity, and cooperativity which is SA-specific such as nanoparticle-SA or mixed-valence SA cooperativity.

Graphical abstract: Cooperativity in supported metal single atom catalysis

Article information

Article type
Minireview
Submitted
22 Sun 2021
Accepted
24 Yan 2021
First published
24 Yan 2021

Nanoscale, 2021,13, 5985-6004

Cooperativity in supported metal single atom catalysis

P. Serp, Nanoscale, 2021, 13, 5985 DOI: 10.1039/D1NR00465D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements