Issue 15, 2021

Single-crystal to single-crystal transformation of a coordination chain to a two-dimensional coordination network through a photocycloaddition reaction

Abstract

Irradiation of single crystals of a ladder-like coordination chain with 365 nm UV light induces a regiospecific photochemical [2 + 2] cycloaddition reaction of each pair of adjacent diolefinic ligands from neighbouring crystallographically equivalent chains and thus affords a two-dimensional (4,4)-connected coordination network through single-crystal to single-crystal transformation.

Graphical abstract: Single-crystal to single-crystal transformation of a coordination chain to a two-dimensional coordination network through a photocycloaddition reaction

Supplementary files

Article information

Article type
Communication
Submitted
17 Yan 2021
Accepted
24 Kul 2021
First published
25 Kul 2021

CrystEngComm, 2021,23, 2783-2787

Single-crystal to single-crystal transformation of a coordination chain to a two-dimensional coordination network through a photocycloaddition reaction

F. Yang, N. Y. Li, Y. Ge and D. Liu, CrystEngComm, 2021, 23, 2783 DOI: 10.1039/D1CE00230A

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