Issue 77, 2016

The role of counter-anions in the kinetics and chirality of porphyrin J-aggregates

Abstract

Kinetics of the growth of TPPS4 porphyrin J-aggregates slow down in the order H2SO4 > HCl > HBr > HNO3 > HClO4, in agreement with the Hofmeister series. The rate constants and the extent of chirality correlate with the structure-making or breaking abilities of the different anions with respect to the hydrogen bonding network of the solvent.

Graphical abstract: The role of counter-anions in the kinetics and chirality of porphyrin J-aggregates

Supplementary files

Article information

Article type
Communication
Submitted
13 Maw 2016
Accepted
24 Mha 2016
First published
25 Mha 2016

Chem. Commun., 2016,52, 11520-11523

The role of counter-anions in the kinetics and chirality of porphyrin J-aggregates

I. G. Occhiuto, R. Zagami, M. Trapani, L. Bolzonello, A. Romeo, M. A. Castriciano, E. Collini and L. Monsù Scolaro, Chem. Commun., 2016, 52, 11520 DOI: 10.1039/C6CC05768C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements