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Abstract | Cited by

A formal γ-alkynylation of ketones via Pd-catalyzed C–C bond-cleavage is presented. The method allows for the coupling of tert-cyclobutanols and bromoacetylenes, giving access to versatile alkynes that are beyond reach otherwise.

Graphical abstract: Formal γ-alkynylation of ketones via Pd-catalyzed C–C cleavage

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