Me3P complexes of p-block Lewis acids SnCl4, SnCl3+ and SnCl22+

Elizabeth MacDonald; Lauren Doyle; Saurabh S. Chitnis; Ulrike Werner-Zwanziger; Neil Burford; Andreas Decken

doi:10.1039/C2CC33206J

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Me₃P complexes of p-block Lewis acids SnCl₄, SnCl₃⁺ and SnCl₂²⁺†‡

Elizabeth MacDonald,^a Lauren Doyle,^a Saurabh S. Chitnis,^b Ulrike Werner-Zwanziger,^a Neil Burford*^b and Andreas Decken^c

Author affiliations

* Corresponding authors

^a Department of Chemistry, Dalhousie University, Halifax, NS, Canada

^b Department of Chemistry, University of Victoria, Victoria, BC, Canada
E-mail: nburford@uvic.ca
Fax: +1 250 721 7147
Tel: +1 250 271 7150

^c Department of Chemistry, University of New Brunswick, Fredericton, NB, Canada

Abstract

Reactions of Me₃P with SnCl₄ in the presence of nAlCl₃ (n = 0, 1, 2) yields a series of P-Sn complexes illustrating new bonding environments for tin.

This article is part of the themed collection: Frontiers in Molecular Main Group Chemistry

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Article information

DOI: https://doi.org/10.1039/C2CC33206J
Article type: Communication
Submitted: 04 Mud 2012
Accepted: 22 Kho 2012
First published: 22 Kho 2012

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Chem. Commun., 2012,48, 7922-7924

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Me₃P complexes of p-block Lewis acids SnCl₄, SnCl₃⁺ and SnCl₂²⁺

E. MacDonald, L. Doyle, S. S. Chitnis, U. Werner-Zwanziger, N. Burford and A. Decken, Chem. Commun., 2012, 48, 7922 DOI: 10.1039/C2CC33206J

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