Two synthetic routes to cationic ruthenium germylene complexes are described. A hydrogen-substituted germylene complex undergoes various additions of the Ge–H bond to
![Graphical abstract: Synthesis and reactivity of cationic ruthenium germylene complexes [Cp*(PiPr3)RuH2( [[double bond, length as m-dash]] GeRR′)]+](/ts/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=C2CC32840B&imageInfo.ImageIdentifier.Year=2012)
![[double bond, length as m-dash]](https://www.rsc.org/images/entities/h2_char_e001.gif)
GeRR′)]+
M. E. Fasulo and T. D. Tilley, Chem. Commun., 2012, 48, 7690 DOI: 10.1039/C2CC32840B
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![[double bond, length as m-dash]](https://www.rsc.org/images/entities/char_e001.gif)
GeRR′)]+
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