Issue 61, 2012
From the journal:

Chemical Communications

Tricationic analogues of boroxines and polyborate anions†‡

Alessandro Del Grosso,a   Ewan R. Clark,a   Nicholas Montoutea  and  Michael J. Ingleson*a  

* Corresponding authors

a Department of Chemistry, University of Manchester, Manchester, UK
E-mail: michael.ingleson@manchester.ac.uk
Fax: +44 (0)161 275 4616
Tel: +44 (0)161 306580

Abstract

Addition of E2O (E = Me3Si or H) to [(pyridyl)BX2][AlX4] (X = Cl or Br) and subsequent heating produced the unprecedented trications [(2,6-lutidine)4B5O6]3+ and [(pyridine)4B3O3]3+.

Graphical abstract: Tricationic analogues of boroxines and polyborate anions

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Article information

DOI
https://doi.org/10.1039/C2CC32605A
Article type
Communication
Submitted
12 Dzi 2012
Accepted
05 Kho 2012
First published
12 Kho 2012

Chem. Commun., 2012,48, 7589-7591

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Tricationic analogues of boroxines and polyborate anions

A. Del Grosso, E. R. Clark, N. Montoute and M. J. Ingleson, Chem. Commun., 2012, 48, 7589 DOI: 10.1039/C2CC32605A

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