Issue 6, 2009

Sulfate anion templation of macrocycles, capsules, interpenetrated and interlocked structures

Abstract

This tutorial review examines the potential of anions, in particular sulfate, to template the formation of complex molecular architectures. Until recently, sulfate has been largely overlooked in this area and the examples described herein demonstrate this anion’s versatility in templating the formation of a diverse range of molecular systems including macrocycles, helixes, molecular capsules, interpenetrated and interlocked assemblies such as catenanes. In addition sulfate has been shown to template the formation of interpenetrated structures on a range of surfaces including gold, polystyrene beads and silicate nanoparticles, highlighting the potential of this anion in the fabrication of functional sensory devices exhibiting highly selective binding behaviour.

Graphical abstract: Sulfate anion templation of macrocycles, capsules, interpenetrated and interlocked structures

Article information

Article type
Tutorial Review
Submitted
11 N’w 2008
First published
27 Kul 2009

Chem. Soc. Rev., 2009,38, 1701-1713

Sulfate anion templation of macrocycles, capsules, interpenetrated and interlocked structures

K. M. Mullen and P. D. Beer, Chem. Soc. Rev., 2009, 38, 1701 DOI: 10.1039/B806041J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements