Selective inclusion of aliphatic alcohols by a diol host compound

Abstract

An aliphatic alcohol mixture is separated using enclathration methods, and the results are explained by means of lattice energy calculations and structural analysis.

References

1. F. Toda, in Comprehensive Supramolecular Chemistry, ed. D. D. MacNicol, F. Toda and R. Bishop, Pergamon, 1996, vol. 6, ch. 15.
2. S. Allenmark and V. Shurig, J. Mater. Chem., 1997, 7, 1955.
3. F. Toda, in Topics in Current Chemistry, Vol. 40, Molecular Inclusion and Molecular Recognition—Clathrates I, Springer-Verlag, Berlin, 1987, ch. 3.
4. S. A. Bourne, L. R. Nassimbeni and F. Toda, J. Chem. Soc., Perkin Trans. 2, 1991, 1335.
5. E. Weber, in Inclusion Compounds, ed. J. L. Atwood, J. E. D. Davies and D. D. MacNicol, Oxford University Press, Oxford, 1991, vol. 4, ch. 5.
6. M. R. Caira, A. Horne, L. R. Nassimbeni, K. Okuda and F. Toda, J. Chem. Soc., Perkin Trans. 2, 1995, 1063.
7. M. R. Caira, A. Horne, L. R. Nassimbeni and F. Toda, J. Chem. Soc., Perkin Trans. 2, 1997, 1717; J. Mater. Chem., 1997, 7, 2145.
8. G. M. Sheldrick, SHELX-86, in Crystallographic Computing 3, ed. G. M. Sheldrick, C. Kruger and R. Goddard, Oxford University Press, Oxford, 1985, p. 175.
9. G. M. Sheldrick, SHELX-93: A Program for Crystal Structure Determination, University of Göttingen, 1993.
10. C. F. Marais, HEENY—Modification of EENY to allow H-bonding calculations, University of Cape Town, 1990.
11. W. D. S. Motherwell, in EENY—Potential Energy Program, Cambridge University, England, unpublished work.
12. E. Giglio, Nature, 1969, 222, 339.
13. A. J. Pertsin and A. I. Kitaigorodsky, The Atom–Atom Potential Method, Chemical Physics 43, Springer-Verlag, Berlin, 1987, ch. 3.
14. A. Vedani and J. D. Dunitz, J. Am. Chem. Soc., 1985, 107, 7653.
15. D. R. Bond and F. Toda, Acta Crystallogr., Sect. C, 1991, 47, 348.