We present an electrochemical platform for achieving attomolar detection by leveraging partitioning kinetics. The partitioning arises from the higher solubility of Cp2*(Fe)II in DCE versus water, allowing enrichment of analyte concentration.
We quantified the dissolution rate of sub-nL oil microdroplets in a bulk aqueous phase based on the evolution of cyclic voltammograms recorded for a redox mediation confined in the microdroplet.
Hybrid binuclear complexes and their ZrIVMIIIMIIMIIZrIV-pentanuclear analogs were prepared using the template reactions of 3-acetylpyrazoloxime with metal(IV) phthalocyaninate on the metal ion as a matrix.
A kinetic study investigating the formation of a [2Fe–2S] compound, 1, with an unusually long Fe⋯Fe distance. 1 holds potential implications for the understanding of S-atom transfer reactions.
The potential for the oxidation shifted cathodically by 590 mV by substituting the exogenous ligand from OAc− to OH−. The potential of the complex with mixed OH−/OAc− is the mean value of the potentials of OH−/OH− and OAc−/OAc− complexes.