Vladimir G. Ilkin, Pavel S. Silaichev, Valery O. Filimonov, Alexey V. Nikulin, Nikolai A. Beliaev, Tetyana V. Beryozkina, Pavel A. Slepukhin, Wim Dehaen and Vasiliy A. Bakulev
New J. Chem., 2026,50, 733-740
Abstract
An azide-free approach toward N-sulfonyl amidines, including phosphorus-containing derivatives based on the reactions of thioamides and thiophosphonyl diamides with iminoiodinanes, was developed.
Rui An, Weihao Cui, Peiming Gu and Meng-Xue Wei
Org. Chem. Front., 2025,12, 6588-6593
Abstract
A practical and convenient approach for the highly stereoselective synthesis of N-sulfonyl amidines via a one-pot multi-component cascade reaction of sulfonyl azides, amines, water, and calcium carbide as an acetylene source has been developed.
Yu Gao, Fang Chai and Chengwei Liu
New J. Chem., 2024,48, 19496-19500
Abstract
Hydroxylamine hydrochloride-catalyzed transamidation of primary thioamides with primary and secondary amines via C(S)–N bond cleavage and formation has been reported.
Chen-Chang Cui, Feng Lin, Lu-Yao Wang, Yin-Ping Liu, Shu-Jiang Tu, Man-Su Tu, Wen-Juan Hao and Bo Jiang
Chem. Commun., 2024,60, 1492-1495
Abstract
A novel base-promoted olefin skeletal rearrangement strategy from para-quinone methides (p-QMs) and N-fluoroarenesulfonamides is reported, enabling direct nitrogen insertion of olefins to produce multiarylated (Z)-N-sulfonyl amidines.
Damijan Knez, Andrej Šterman, Izidor Sosič, Franc Perdih, Gonzalo D. Nuñez, Tilen Knaflič, Denis Arčon, Maria Besora, Jorge J. Carbó, Elena Fernández and Zdenko Časar
Chem. Sci., 2025,16, 12012-12023
Abstract
Primary trifluoroborate-iminiums are transformed into N-sulfonyl amidines in an azide- and transition-metal-free C(sp2)–N bond-forming reaction under mild conditions. The mechanism was elucidated via NMR, mass spectrometry and DFT calculations.
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