Low-cost polyanion cathodes for sodium ion batteries: challenges, strategies, and progress

Sizhen Chen, Xiang Tan, Jun Zeng, Kai Wang, Sihua Hu, Yipo Peng and Jun Liu

J. Mater. Chem. A, 2025, 13, 37730
DOI: 10.1039/D5TA05622E

Critical review of the recent progress and challenges of polyanion Na3V2(PO4)3 cathode materials in rechargeable sodium-ion batteries

Ranjit S. Kate, Harsharaj S. Jadhav, Ujjwala P. Chothe, Kaustav Bhattacharjee, Milind V. Kulkarni, Ramesh J. Deokate, Bharat B. Kale and Ramchandra S. Kalubarme

J. Mater. Chem. A, 2024, 12, 7418
DOI: 10.1039/D3TA07545A

Role of the Mn substituent in Na3V2(PO4)3 for high-rate sodium storage

Jae-Sang Park, Jongsoon Kim, Jae Hyeon Jo and Seung-Taek Myung

J. Mater. Chem. A, 2018, 6, 16627
DOI: 10.1039/C8TA06162A

Doping engineering of phosphorus-based polyanion-type cathodes for sodium storage: a review

Xiaoxue Wang, Yuhui Xu, Yukun Xi, Xiaoli Yang, Jingjing Wang, Xing Huang, Wenbin Li, Kaihua Xu, Kun Zhang, Ruixian Duan, Dongzhu Liu, Ningjing Hou, Zihao Yang, Hui Wang and Xifei Li

J. Mater. Chem. A, 2024, 12, 9268
DOI: 10.1039/D4TA00652F

Research progress on vanadium-based cathode materials for sodium ion batteries

Qinghong Wang, Jiantie Xu, Wenchao Zhang, Minglei Mao, Zengxi Wei, Lei Wang, Chunyu Cui, Yuxuan Zhu and Jianmin Ma

J. Mater. Chem. A, 2018, 6, 8815
DOI: 10.1039/C8TA01627E

Unexpectedly high electrochemical performances of a monoclinic Na2.4V2(PO4)3/conductive polymer composite for Na-ion batteries

Yongseok Lee, Jung-Keun Yoo, Youngseok Oh, Hyunyoung Park, Wonseok Go, Seung-Taek Myung and Jongsoon Kim

J. Mater. Chem. A, 2018, 6, 17571
DOI: 10.1039/C8TA06238B

Recent progress in alkali metal (Li/Na/K) hybrid-ion batteries: pioneering the future of energy storage

Yan Zhang, Rui Cao, Chen Ouyang, Libing Jiang, Yi Wang, Mei Yang and Hui Xia

J. Mater. Chem. A, 2025, 13, 3973
DOI: 10.1039/D4TA06190J

Application of metal organic frameworks (MOFs) and their derivatives in the cathode materials of aqueous zinc-ion batteries

Pingchun Guo, Shisong Ouyang, Hedong Jiang, Jiake Li, Hua Zhu and Yanxiang Wang

J. Mater. Chem. C, 2024, 12, 18591
DOI: 10.1039/D4TC03273J

Advances in the application of first principles calculations to phosphate-based NASICON battery materials

Zhongyi Cui, Shilong Sun, Gexuan Ning, Lisi Liang, Zeming Wang, Jiangyu Qiao, Lixing Zhang, Jin Chen and Zhuyue Zhang

J. Mater. Chem. A, 2024, 12, 29335
DOI: 10.1039/D4TA04943H

Na3V2(PO4)3: an advanced cathode for sodium-ion batteries

Xianghua Zhang, Xianhong Rui, Dong Chen, Huiteng Tan, Dan Yang, Shaoming Huang and Yan Yu

Nanoscale, 2019, 11, 2556
DOI: 10.1039/C8NR09391A

Doping modification of sodium superionic conductor Na3V2(PO4)3 cathodes for sodium-ion batteries: a mini-review

Yurui Shao, Yijun Qian, Tianshu Zhang, Pengcheng Zhang, Haocong Wang, Tao Qian and Chenglin Yan

Inorg. Chem. Front., 2024, 11, 4552
DOI: 10.1039/D4QI01141D

Modulation of the Crystal Structure and Ultralong Life Span of a Na3V2(PO4)3-Based Cathode for a High-Performance Sodium-Ion Battery by Niobium–Vanadium Substitution

Linnan Bi, Xiaoqing Liu, Xiaoyan Li, Bingbing Chen, Qiaoji Zheng, Fengyu Xie, Yu Huo and Dunmin Lin

Ind. Eng. Chem. Res., 2020, 59, 21039
DOI: 10.1021/acs.iecr.0c04187

Multi-Ion Strategies Toward Advanced Rechargeable Batteries: Materials, Properties, and Prospects

Zilu Wang, Yu Li, Qiannan Zhou, Qiaojun Li, Ran Zhao, Zhixu Qiu, Ripeng Zhang, Yufeng Sun, Feng Wu, Chuan Wu and Ying Bai

Energy Mater Adv, 2024, 5
DOI: 10.34133/energymatadv.0109

Recent advances of in-situ spectroscopic analysis for cathode materials of sodium-ion batteries

Jing Cui, Zhaojin Li, Di Zhang, Yusheng Wu and Bo Wang

Journal of Energy Storage, 2024, 97, 112734
DOI: 10.1016/j.est.2024.112734

A critical review of vanadium-based electrode materials for rechargeable magnesium batteries

Xiu-Fen Ma, Hong-Yi Li, Weiwei Ren, Daibo Gao, Fuyu Chen, Jiang Diao, Bing Xie, Guangsheng Huang, Jingfeng Wang and Fusheng Pan

Journal of Materials Science & Technology, 2023, 153, 56
DOI: 10.1016/j.jmst.2022.12.052

Revealing Cathode–Electrolyte Interface on Flower‐Shaped Na3V2(PO4)3/C Cathode through Cryogenic Electron Microscopy

Muhammad Ihsan-Ul-Haq, Jiang Cui, Nauman Mubarak, Mengyang Xu, Xi Shen, Zhengtang Luo, Baoling Huang and Jang-Kyo Kim

Adv Energy and Sustain Res, 2021, 2
DOI: 10.1002/aesr.202100072

Recent advances in high energy-density cathode materials for sodium-ion batteries

Yingchun Lyu, Yuchen Liu, Zhuo-Er Yu, Na Su, Yang Liu, Wenxian Li, Qian Li, Bingkun Guo and Bin Liu

Sustainable Materials and Technologies, 2019, 21, e00098
DOI: 10.1016/j.susmat.2019.e00098

Recent advances of NASICON-Na3V2(PO4)3 as cathode for sodium-ion batteries: Synthesis, modifications, and perspectives

Bowen Zhang, Kaixuan Ma, Xin Lv, Kun Shi, Yuan Wang, Zhiyang Nian, Yuehua Li, Ling Wang, Lei Dai and Zhangxing He

Journal of Alloys and Compounds, 2021, 867, 159060
DOI: 10.1016/j.jallcom.2021.159060

Hi Gh-Performance Li/Na Hybrid-Ion Batteries with Nonstoichiometric Li2.7v2.1(Po4)3/C As Cathode Material

Yinshen Liu, Wenjing Zhao, Kunpeng Ding, Sai Qin, Danyi Liu, Ying Chen, Yicheng Liu, Qingyu Xu, Kai Shen and Qi Fan

SSRN Journal, 2022
DOI: 10.2139/ssrn.4014080

Recent progress and prospects of NASICON framework electrodes for Na-ion batteries

Raghunayakula Thirupathi, Vandana Kumari, Sumanta Chakrabarty and Shobit Omar

Progress in Materials Science, 2023, 137, 101128
DOI: 10.1016/j.pmatsci.2023.101128

Recent Development of Phosphate Based Polyanion Cathode Materials for Sodium‐Ion Batteries

Zishan Ahsan, Zhenfei Cai, Shuai Wang, Muhammad Moin, Haichuan Wang, Dongming Liu, Yangzhou Ma, Guangsheng Song and Cuie Wen

Advanced Energy Materials, 2024, 14
DOI: 10.1002/aenm.202400373

Dual-site doping strategy for enhancing the rate and cycling performance of Na3V2(PO4)2F3 cathode

Yanyan Li, Qiong Liu, Tong Liu, Juanjuan Wang, Yingying Liu, Yaxuan Cai, Haiting Lv, Kangzhe Cao and Yang Fan

Journal of Power Sources, 2025, 652, 237694
DOI: 10.1016/j.jpowsour.2025.237694

Vanadium-based polyanionic compounds as cathode materials for sodium-ion batteries: Toward high-energy and high-power applications

Zhiqiang Lv, Moxiang Ling, Meng Yue, Xianfeng Li, Mingming Song, Qiong Zheng and Huamin Zhang

Journal of Energy Chemistry, 2021, 55, 361
DOI: 10.1016/j.jechem.2020.07.008

Interfacial stability analysis between Ca-doped Na3PS4 solid electrolyte and Na anode from first-principles calculations

Han Li, Zhonglin Zhang, Bin Liu, Jingli Liu, Bingbing Chen and Jianqiu Zhou

Computational Materials Science, 2023, 216, 111848
DOI: 10.1016/j.commatsci.2022.111848

Redox Couple Modulation in NASICON Phosphates toward High-Performance Cathodes for Na-Ion Batteries

Dashan Fan, Qiuyu Shen, Han Li, Xuanhui Qu, Lifang Jiao and Yongchang Liu

Energy Mater Adv, 2024, 5
DOI: 10.34133/energymatadv.0073

Carbon-coating-increased working voltage and energy density towards an advanced Na3V2(PO4)2F3@C cathode in sodium-ion batteries

Zhen-Yi Gu, Jin-Zhi Guo, Zhong-Hui Sun, Xin-Xin Zhao, Wen-Hao Li, Xu Yang, Hao-Jie Liang, Chen-De Zhao and Xing-Long Wu

Science Bulletin, 2020, 65, 702
DOI: 10.1016/j.scib.2020.01.018

Dual carbon skeleton supported NVPFO sodium-ion battery cathode with high rate capability, superior cycling performance, and wide temperature adaptability

Jianhui Ma, Xihong Zu, Xueqing Qiu and Wenli Zhang

Chemical Engineering Journal, 2024, 493, 152792
DOI: 10.1016/j.cej.2024.152792

The Distance Between Phosphate‐Based Polyanionic Compounds and Their Practical Application For Sodium‐Ion Batteries

Zhiqiang Hao, Xiaoyan Shi, Zhuo Yang, Xunzhu Zhou, Lin Li, Chang‐Qi Ma and Shulei Chou

Advanced Materials, 2024, 36
DOI: 10.1002/adma.202305135

Zn-doping Effects of Na-rich Na3+xV2-xZnx(PO4)3/C cathodes for Na-Ion Batteries: Lattice distortion induced by doping site and enhanced electrochemical performance

Xinran Li, Cheng Chen, Jian Yang, Zixuan Fang, Shumao Zeng, Tingting Feng, Haiping Zhou, Shu Zhang and Mengqiang Wu

Journal of Colloid and Interface Science, 2022, 616, 246
DOI: 10.1016/j.jcis.2021.12.123

Phosphorus-doped graphene-improved Na3V2(PO4)3@C nanocomposite possessing high-rate performance for electrochemical energy storage

Shanshan Jiang and Yuansheng Wang

Ceramics International, 2019, 45, 11600
DOI: 10.1016/j.ceramint.2019.03.031

Utilizing Titanium–Vanadium Coprecipitation for the Preparation of High-Performance Sodium Vanadium Phosphate Cathode Materials from Low-Purity Vanadium Sources

Weijian Song, Haoyu Li, Jiahui Zhao, Zhuangzhi Li, Changyan Hu and Zhenguo Wu

Ind. Eng. Chem. Res., 2026, 65, 8318
DOI: 10.1021/acs.iecr.6c00497

Boosted electrochemical performance of Na3V2(PO4)3 at low temperature through synergistical F substitution and construction of interconnected nitrogen-doped carbonaceous network

Jiabao Li, Ziqian Li, Shaocong Tang, Tianyi Wang, Likun Pan and Chengyin Wang

Journal of Materials Science & Technology, 2023, 150, 159
DOI: 10.1016/j.jmst.2022.11.048

Efficient Preparation of Conductive Polymer-Intercalated Vanadium Pentoxide Composite Materials for Aqueous Zinc Metal Batteries

Qi Sheng, Peng Xie, Bin Wang and Ding Chen

ACS Omega, 2026, 11, 25810
DOI: 10.1021/acsomega.6c01112

Porous Na3V2(PO4)3/C as cathode material for high-rate sodium-ion batteries by sacrificed template method

Shuo Bao, Ying-ying Huang, Shao-hua Luo and Jin-lin Lu

Ionics, 2020, 26, 5011
DOI: 10.1007/s11581-020-03635-0

Biomimetic Synthesis of Craspedia Globosa-Shaped Na ₃V ₂(PO ₄) ₃ with High Performance for Sodium Ion Batteries

Shiqi Sun, Yanjun Chen, Zeyi Tian, Xiaomei Jiang, Jiahao Li, Zhen Tian, Que Huang, Changcheng Liu, Yanzhong Wang and Li Guo

SSRN Journal, 2021
DOI: 10.2139/ssrn.3993323

Doping Regulation in Polyanionic Compounds for Advanced Sodium‐Ion Batteries

Lifen Xiao, Fangjie Ji, Jiexin Zhang, Xumiao Chen and Yongjin Fang

Small, 2023, 19
DOI: 10.1002/smll.202205732

Polyanion Sodium Vanadium Phosphate for Next Generation of Sodium‐Ion Batteries—A Review

Gongxuan Chen, Qing Huang, Tian Wu and Li Lu

Adv Funct Materials, 2020, 30
DOI: 10.1002/adfm.202001289

Crystal defect modulation in cathode materials for non-lithium ion batteries: Progress and challenges

Fangyu Xiong, Shuangshuang Tan, Xuhui Yao, Qinyou An and Liqiang Mai

Materials Today, 2021, 45, 169
DOI: 10.1016/j.mattod.2020.12.002

Biomimetic synthesis of craspedia globosa-shaped Na3V2(PO4)3 with high performance for sodium ion batteries

Shiqi Sun, Yanjun Chen, Zeyi Tian, Xiaomei Jiang, Jiahao Li, Zhen Tian, Que Huang, Changcheng Liu, Yanzhong Wang and Li Guo

Journal of Alloys and Compounds, 2022, 909, 164719
DOI: 10.1016/j.jallcom.2022.164719

A Comprehensive Review on Strategies for Enhancing the Performance of Polyanionic-Based Sodium-Ion Battery Cathodes

Anupama Joy, Khusboo Kumari, Fatma Parween, Mst Shubnur Sultana and Ganesh Chandra Nayak

ACS Omega, 2024, 9, 22509
DOI: 10.1021/acsomega.4c02709

Influence of Na-substitution on the structure and electrochemical properties of layered oxides K0.67Ni0.17Co0.17Mn0.66O2 cathode materials

Cai-ling Liu, Shao-hua Luo, Hong-bo Huang, Yu-chun Zhai and Zhao-wen Wang

Electrochimica Acta, 2018, 286, 114
DOI: 10.1016/j.electacta.2018.08.028

Low-valence lithium doping modulates the Mn3+/Mn4+ redox couple and stabilizes the P2 framework for high-rate sodium-ion cathodes

Yunqin Yang, Minyi Liao, Fanjun Tang, Xuanchen Wei, Donglou Ren and Tianquan Liang

Electrochimica Acta, 2026, 565, 148783
DOI: 10.1016/j.electacta.2026.148783

Lattice‐Interface Dual Engineering Unlocking Quasi‐Zero‐Strain and High‐Rate Zinc‐Ion Storage in Polyanionic Cathode

Qiaofeng Huang, Sheng Ouyang, Jiarui Lin, Rui Jiang, Jiajie Zhou, Xiaoyan Shi, Junling Xu, Lianyi Shao and Zhipeng Sun

Advanced Science, 2026, 13
DOI: 10.1002/advs.202521583

Rechargeable Sodium‐Based Hybrid Metal‐Ion Batteries toward Advanced Energy Storage

Zhuo Yang, Xiao‐Hao Liu, Xiang‐Xi He, Wei‐Hong Lai, Li Li, Yun Qiao, Shu‐Lei Chou and Minghong Wu

Adv Funct Materials, 2021, 31
DOI: 10.1002/adfm.202006457

NMR Evidence for the Multielectron Reaction Mechanism of Na3V2(PO4)3 Cathode and the Impact of Polyanion Site Substitution

Qing Qiu, Chao Li, Hui Liu, Yuxin Liao, Chong Zhao, Fushan Geng, Ming Shen, Jingxin Li, Wei Tong and Bingwen Hu

J. Phys. Chem. C, 2021, 125, 15200
DOI: 10.1021/acs.jpcc.1c04099

Synergistically Boosting Sodium-Storage Performance of Na3V2(PO4)3 by Regulating Na Sites and Constructing 3D Interconnected Carbon Nanosheet Frameworks

Peng Chen, Chunyang Wu, Zuyong Wang, Shuigen Li, Xiongwen Xu, Jian Tu and Yuan-Li Ding

ACS Appl. Energy Mater., 2022, 5, 2542
DOI: 10.1021/acsaem.1c04061

Enhancing Na-storage property of Na3V2(PO4)3 via porous structure Design：From the perspective of carbon source optimization

Wenjiao Li, Xiaoping Yang, Jingjing He, Chao Zhao, Yuanpeng Cao, Can Wu, Xi Yang, Ding Wang, Xianshu Wang, Yingjie Zhang, Peng Dong and Jianguo Duan

Journal of Power Sources, 2024, 610, 234732
DOI: 10.1016/j.jpowsour.2024.234732

Enhanced Cycling Stability and Rate Capability in a La-Doped Na3V2(PO4)3/C Cathode for High-Performance Sodium Ion Batteries

Linnan Bi, Xiaoyan Li, Xiaoqin Liu, Qiaoji Zheng and Dunmin Lin

ACS Sustainable Chem. Eng., 2019, 7, 7693
DOI: 10.1021/acssuschemeng.8b06385

Synergistic Effect of Ternary Substitution in Na3V2(PO4)3 for High-Rate and Long-Life Anode-Free SIBs

Ruoyu Chen, Dongdong Li, Xinyu Zhang, Shuoxiao Zhang, Xingyu Wang, Shilin Li, Il’ya A. Gural’skiy, Igor V. Zatovsky, Wei Han and Denys Butenko

ACS Appl. Mater. Interfaces, 2025, 17, 45859
DOI: 10.1021/acsami.5c08411

Na3V2(PO4)3 cathode materials for advanced sodium-ion batteries: Modification strategies and density functional theory calculations

Zhaoyang Wang, Zhi Li, Zijuan Du, Jiajun Geng, Wei Zong, Ruwei Chen, Haobo Dong, Xuan Gao, Fangjia Zhao, Tianlei Wang, Tasnim Munshi, Lingyang Liu, Pengfang Zhang, Wenjing Shi, Dong Wang, Yaoyao Wang, Min Wang, Fangyu Xiong and Guanjie He

Journal of Colloid and Interface Science, 2025, 682, 760
DOI: 10.1016/j.jcis.2024.11.212

Review of vanadium-based electrode materials for rechargeable aqueous zinc ion batteries

Ying Liu and Xiang Wu

Journal of Energy Chemistry, 2021, 56, 223
DOI: 10.1016/j.jechem.2020.08.016

Achieving the Stable Structure and Superior Performance of Na3V2(PO4)2O2F Cathodes via Na-Site Regulation

Jing Liu, Lu-Lu Zhang, Xing-Zhong Cao, Xing Lin, Yue Shen, Peng Zhang, Cheng Wei, Yang-Yang Huang, Wei Luo and Xue-Lin Yang

ACS Appl. Energy Mater., 2020, 3, 7649
DOI: 10.1021/acsaem.0c01077

Element Optimization in NASICON Phosphates Enhances Sodium Storage Performance

Yuanxutong Wen, Xiangpeng Kong, Qiang Rong, Peiling Lin, Qunxiong Shi, Ze Li, Xuping Su, Jiaqi Meng, Qidi Wang, Zimeng Luo, Xingxing Jiao, Zhongxiao Song, Yangyang Liu, Shujiang Ding and Long Li

Small, 2025, 21
DOI: 10.1002/smll.202502098

Low-Cost, the Key for the Commercialization of the Na3V2(PO4)3 Cathode

Fangying Xiong, Zhuangzhi Li, Haoyu Li, Fa He, Ting Chen, Benhe Zhong, Zhenguo Wu and Xiaodong Guo

Ind. Eng. Chem. Res., 2024, 63, 3425
DOI: 10.1021/acs.iecr.3c04208

NASICON-type NaMo2(PO4)3: Electrochemical activity of the Mo+4 polyanion compound in Na-cell

Rodion V. Panin, Oleg A. Drozhzhin, Stanislav S. Fedotov, Nellie R. Khasanova and Evgeny V. Antipov

Electrochimica Acta, 2018, 289, 168
DOI: 10.1016/j.electacta.2018.09.045

Research Progress in Multielectron Reactions in Polyanionic Materials for Sodium‐Ion Batteries

Rui Liu, Ziteng Liang, Zhengliang Gong and Yong Yang

Small Methods, 2019, 3
DOI: 10.1002/smtd.201800221

Controllable Configuration of Constitutional Units in Vanadium/Iron‐Based Polyanionic Compounds for Sodium‐Ion Storage

Bochao Chen, Jiahao Wang, Zhiyuan Xu, Jie Miao, Yong Lu, Zhenhua Yan, Kai Zhang and Jun Chen

Advanced Materials, 2025, 37
DOI: 10.1002/adma.202509966

Progress in Sodium‐Ion Batteries: A Focus on Phosphate‐Based Cathodes and Their Interaction With Electrolytes

Mushtaq Ahmad Dar, Ibrahim Abdullah Alnaser, Dong-Wan Kim and Sami-Ullah Rather

International Journal of Energy Research, 2024, 2024
DOI: 10.1155/er/9198966

Partial Modification Strategies of NASICON-Type Na3V2(PO4)3 Materials for Cathodes of Sodium-Ion Batteries: Progress and Perspectives

Qingke Huang, Zhihua Hu, Kai Chen, Zeng Zeng, Yan Sun, Qingquan Kong, Wei Feng, Ke Wang, Zhuangzhi Li, Zhenguo Wu, Ting Chen and Xiaodong Guo

ACS Appl. Energy Mater., 2023, 6, 2657
DOI: 10.1021/acsaem.2c04083

Ultrafine Na3V2(PO4)3@C nanoparticles embedded in boron-doped graphene as high-rate and long cycle-life cathode material for sodium-ion batteries

Qin Zeng, Ligang Luo, Zhihao Yu and Linhua Jiang

Solid State Ionics, 2018, 323, 92
DOI: 10.1016/j.ssi.2018.05.023

Electrode Design for High-Performance Sodium-Ion Batteries: Coupling Nanorod-Assembled Na3V2(PO4)3@C Microspheres with a 3D Conductive Charge Transport Network

Zhiqiang Lv, Moxiang Ling, Hongming Yi, Huamin Zhang, Qiong Zheng and Xianfeng Li

ACS Appl. Mater. Interfaces, 2020, 12, 13869
DOI: 10.1021/acsami.9b22746

Nano self-assembly of fluorophosphate cathode induced by surface energy evolution towards high-rate and stable sodium-ion batteries

Zhen-Yi Gu, Yong-Li Heng, Jin-Zhi Guo, Jun-Ming Cao, Xiao-Tong Wang, Xin-Xin Zhao, Zhong-Hui Sun, Shuo-Hang Zheng, Hao-Jie Liang, Bo Li and Xing-Long Wu

Nano Res., 2023, 16, 439
DOI: 10.1007/s12274-022-4687-6

Langmuir-Blodgett deposited Na3V2(PO4)3-MnO2 nanocomposite thin film electrodes for hybrid energy storage application

Muthukumar Divagar, Nagamony Ponpandian and Chinnuswamy Viswanathan

Materials Science and Engineering: B, 2021, 270, 115229
DOI: 10.1016/j.mseb.2021.115229

Mixed sodium-lithium vanadium fluorophosphates Na3-xLixV2(PO4)2F3: The origin of the excellent high-rate performance

N.V. Kosova and D.O. Rezepova

Journal of Power Sources, 2018, 408, 120
DOI: 10.1016/j.jpowsour.2018.09.088

Heteroatom Doping: An Effective Way to Boost Sodium Ion Storage

Yu Li, Minghua Chen, Bo Liu, Yan Zhang, Xinqi Liang and Xinhui Xia

Advanced Energy Materials, 2020, 10
DOI: 10.1002/aenm.202000927

Regulation on Morphology and Electronic Structure Design of Vanadium‐Based Sodium Phosphate Cathodes for High‐Performance Sodium‐Ion Batteries

Xinran Qi, Baoxiu Hou, Ruifang Zhang, Xiaocui Chen, Zhenrong Fu, Xin Zhou, Haiyan Liu, Ningzhao Shang, Shuaihua Zhang, Longgang Wang, Chunsheng Li, Jianjun Song, Shuangqiang Chen and Xiaoxian Zhao

Carbon Energy, 2025, 7
DOI: 10.1002/cey2.70030

Structural Evolution of Lithium-Exchanged Na3(VO)2(PO4)2F Cathode under Operation in Sodium Ion Batteries

Qinlong Chen, Lina Gao, Tingyu Liu, Alessandro Marchetti, Juner Chen, Huilin Pan and Xueqian Kong

J. Phys. Chem. Lett., 2024, 15, 1062
DOI: 10.1021/acs.jpclett.3c03191

Oxygen Vacancy Engineering in Na3V2(PO4)3 for Boosting Sodium Storage Kinetics

Minxia Jiang, Dan Xu, Baifeng Yang, Chaozhen Zhang and Minhua Cao

Adv Materials Inter, 2021, 8
DOI: 10.1002/admi.202100188

Thiourea induced the N/S co-doped carbon skeleton suppressing the dissolution of V to boost superior cyclic stability of Na3V2(PO4)3

Tao Zhou and Yanjun Chen

Carbon, 2024, 218, 118778
DOI: 10.1016/j.carbon.2023.118778

Optimizing Sc-Doped Na3V2(PO4)2F3/C as a High-Performance Cathode Material for Sodium-Ion Battery Applications

Shaokang Guo, Jian Peng, Neeraj Sharma, Jiaqi Pan, Yi Liao, Xinhao An, Hanchi Li, Zhisong Ge, Chunliang Zhou, Wen Liang Tan and Junnan Liu

Chem. Mater., 2025, 37, 1500
DOI: 10.1021/acs.chemmater.4c02872

Emerging high-entropy strategy: A booster to the development of cathode materials for power batteries

Liping Huang, Jingting Zhu, Ji-Xuan Liu, Houzheng Wu and Guo-Jun Zhang

Journal of Advanced Ceramics, 2024, 13, 1093
DOI: 10.26599/JAC.2024.9220913

Recent research progress in the application of Na3V2(PO4)2F3 cathode materials in sodium-ion batteries: synthesis, modification, and battery optimization

Yining Liang, Lin Xu, Zhengjian Chen, De Ning and Zhipeng Sun

Energy Mater., 2025, 5
DOI: 10.20517/energymater.2024.306

High-performance Li/Na hybrid-ion batteries with nonstoichiometric Li2.7V2.1(PO4)3/C as cathode material

Yinshen Liu, Wenjing Zhao, Kunpeng Ding, Sai Qin, Danyi Liu, Ying Chen, Yicheng Liu, Qingyu Xu, Kai Shen and Qi Fan

Journal of Alloys and Compounds, 2022, 914, 165182
DOI: 10.1016/j.jallcom.2022.165182

Will Vanadium‐Based Electrode Materials Become the Future Choice for Metal‐Ion Batteries?

Dong Zhao, Chunlei Wang, Yan Ding, Mingyue Ding, Yuliang Cao and Zhongxue Chen

ChemSusChem, 2022, 15
DOI: 10.1002/cssc.202200479

Sandwich structure endows Na3V2(PO4)3 cathodes with superb sodium storage

Fengjie Gao, Di Chen, Hui Ying Yang, Yanfeng Yin, Caiyan Yu and Ying Bai

Applied Physics Letters, 2022, 121
DOI: 10.1063/5.0100982

Metal-organic framework-derived structures for next-generation rechargeable batteries

Wenhui Shi, Xilian Xu, Lin Zhang, Wenxian Liu and Xiehong Cao

Funct. Mater. Lett., 2018, 11, 1830006
DOI: 10.1142/S1793604718300062

Progress and prospect for NASICON-type Na3V2(PO4)3 for electrochemical energy storage

Qiong Zheng, Hongming Yi, Xianfeng Li and Huamin Zhang

Journal of Energy Chemistry, 2018, 27, 1597
DOI: 10.1016/j.jechem.2018.05.001

Li–Na-based hybrid battery

Kumlachew Zelalem Walle, Jayaraman Pandeeswari, Gunamony Jenisha and Masashi Kotobuki

Funct. Mater. Lett., 2023, 16
DOI: 10.1142/S1793604723400118

Heterostructure of Ta5+-substituted Na3V2(PO4)3–TaN promoting the activation of V4+/V5+ redox couple for high performance sodium-ion batteries

Tao Zhou, Qiang Bai and Yanjun Chen

Journal of Power Sources, 2024, 604, 234472
DOI: 10.1016/j.jpowsour.2024.234472