Sr5TeO2(BO3)4 and NaSr5(BO3)(SiO4)2: two inorganic metal borate derivatives with diverse zero dimensional anions

Ruling Tang, Chunli Hu, Jianghe Feng, Zhi Fang, Yan Chen, Fang Kong and Jianggao Mao

Dalton Trans., 2020, 49, 3743
DOI: 10.1039/C9DT03839F

Synthesis, structures, and properties of two magnesium silicate fluorides Mg5(SiO4)2F2and Mg3SiO4F2

Ni Zhen, Kui Wu, Qiang Li, Shilie Pan, Wenhui Gao and Zhihua Yang

New J. Chem., 2015, 39, 8866
DOI: 10.1039/C5NJ01911G

Na10Zn(NO3)4(SO3S)4: a nonlinear optical crystal combining inorganic π-conjugated and non-π-conjugated heteroanion groups

Zihao Yu, Qingran Ding, Yuhang Jiang, Weiqi Huang, Changsheng Yang, Sangen Zhao and Junhua Luo

Inorg. Chem. Front., 2024, 11, 107
DOI: 10.1039/D3QI02107F

CO(NH2)2·NH4Cl: an ultraviolet birefringent material with conjugated CO groups

Ya Wang, Jian Han, Abudukadi Tudi, Zhizhong Zhang, Zhihua Yang and Shilie Pan

CrystEngComm, 2019, 21, 6072
DOI: 10.1039/C9CE01350D

Computationally assisted multistage design and prediction driving the discovery of deep-ultraviolet nonlinear optical materials

Zhihua Yang and Shilie Pan

Mater. Chem. Front., 2021, 5, 3507
DOI: 10.1039/D0QM01109F

Mg2Pb2Si2O7F2: a new lead-containing alkali earth metal silicate fluoride with a short cutoff edge

Zhiyuan Zhang, Lihan Deng, Die Xu, Mei Hu, Zhencheng Wu, Xin Su and Yineng Huang

New J. Chem., 2023, 47, 17413
DOI: 10.1039/D3NJ03141A

Na3B4O7X (X = Cl, Br): two new borate halides with a 1D Na-X (X = Cl, Br) chain formed by the face-sharing XNa6octahedra

Chunyan Bai, Shujuan Han, Shilie Pan, Bingbing Zhang, Yun Yang, Lin Li and Zhihua Yang

RSC Adv., 2015, 5, 12416
DOI: 10.1039/C4RA16639F

The first investigation of europium silicate melilite for second-order nonlinear optical application: experimental and theoretical studies

Yang Chi, Huai-Guo Xue and Sheng-Ping Guo

Dalton Trans., 2018, 47, 13434
DOI: 10.1039/C8DT02701C

Li3AlSiO5: the first aluminosilicate as a potential deep-ultraviolet nonlinear optical crystal with the quaternary diamond-like structure

Xinglong Chen, Fangfang Zhang, Lili Liu, Bing-Hua Lei, Xiaoyu Dong, Zhihua Yang, Hongyi Li and Shilie Pan

Phys. Chem. Chem. Phys., 2016, 18, 4362
DOI: 10.1039/C5CP06884C

LiRb2PO4: a new deep-ultraviolet nonlinear optical phosphate with a large SHG response

Lin Li, Ying Wang, Bing-Hua Lei, Shujuan Han, Zhihua Yang, Hongyi Li and Shilie Pan

J. Mater. Chem. C, 2017, 5, 269
DOI: 10.1039/C6TC04565K

Ba3Ca4(BO3)3(SiO4)Cl: a new non-centrosymmetric complex alkaline-earth metal borosilicate chloride with a deep-ultraviolet cut-off edge

Zixiu Lu, Fangfang Zhang, Abudukadi Tudi, Sujuan Yu, Zhihua Yang and Shilie Pan

Inorg. Chem. Front., 2019, 6, 2200
DOI: 10.1039/C9QI00670B

Ba7(BO3)3GeO4X (X = Cl, Br): borogermanate halides with rigid GeO4tetrahedra and flexible XBa6octahedra

Ming Wen, Zhipeng Lian, Hongping Wu, Xin Su, Qingfeng Yan, Juanjuan Lu, Zhihua Yang and Shilie Pan

RSC Adv., 2015, 5, 53448
DOI: 10.1039/C5RA07450A

From silicates to oxonitridosilicates: improving optical anisotropy for phase-matching as ultraviolet nonlinear optical materials

Xiaodong Zhang, Lichao Guo, Bingbing Zhang, Jin Yu, Ying Wang, Kui Wu, Hai-jun Wang and Ming-Hsien Lee

Chem. Commun., 2021, 57, 639
DOI: 10.1039/D0CC07269A

Macroscopic polarity control with alkali metal cation size and coordination environment in a series of tin iodates

Yeong Hun Kim, T. Thao Tran, P. Shiv Halasyamani and Kang Min Ok

Inorg. Chem. Front., 2015, 2, 361
DOI: 10.1039/C4QI00243A

[GaF(H2O)][IO3F]: a promising NLO material obtained by anisotropic polycation substitution

Qian-Ming Huang, Chun-Li Hu, Bing-Ping Yang, Zhi Fang, Yuan Lin, Jin Chen, Bing-Xuan Li and Jiang-Gao Mao

Chem. Sci., 2021, 12, 9333
DOI: 10.1039/D1SC01401C

AZn2(BO3)Si2O5 (A = Rb, Cs): first examples of KBe2BO3F2 structure type in the borosilicate family exhibiting a deep-ultraviolet cutoff edge

Tuohetijiang Baiheti, Abudukadi Tudi, Jian Han, Zhihua Yang and Shilie Pan

J. Mater. Chem. C, 2022, 10, 1727
DOI: 10.1039/D1TC05529A

Synthesis, characterization and crystal structure of a new mixed alkali and alkaline-earth metal borate Rb9Ba24(BO3)19

Xiaowen Niu and Li Wang

New J. Chem., 2020, 44, 3882
DOI: 10.1039/C9NJ06320J

Synthesis, characterization and theoretical studies of nonlinear optical crystal Sr2B5O9(OH)·H2O

Fangyuan Zhang, Fangfang Zhang, Jing Qun, Shilie Pan, Zhihua Yang and Dianzeng Jia

Phys. Chem. Chem. Phys., 2015, 17, 10489
DOI: 10.1039/C5CP00864F

Alkali metal–alkaline earth metal borate crystal LiBa3(OH)(B9O16)[B(OH)4] as a new deep-UV nonlinear optical material

Chao Wu, Junling Song, Longhua Li, Mark G. Humphrey and Chi Zhang

J. Mater. Chem. C, 2016, 4, 8189
DOI: 10.1039/C6TC02306A

Ba4Bi2(Si8−xB4+xO29) (x = 0.09): a new acentric metal borosilicate as a promising nonlinear optical material

Ru-Ling Tang, Chun-Li Hu, Fei-Fei Mao, Jiang-He Feng and Jiang-Gao Mao

Chem. Sci., 2019, 10, 837
DOI: 10.1039/C8SC04342F

Borosilicates as deep-ultraviolet transparent nonlinear optical crystals: Structural motifs, performance limits and future directions

Yangfeifei Ou, Xiao-Liang Zhou, You-Zhao Lan and Jian-Wen Cheng

Chinese Journal of Structural Chemistry, 2025, 44, 100708
DOI: 10.1016/j.cjsc.2025.100708

White‐Light Emission from a Semi‐Conductive Borate‐Stannate

Yuan Lin, Guan‐E Wang, Chun‐Li Hu, Jiang‐He Feng, Li‐Na Li and Jiang‐Gao Mao

Angew Chem Int Ed, 2019, 58, 13390
DOI: 10.1002/anie.201907650

The role of cations in second-order nonlinear optical materials based on π-conjugated [BO 3 ] 3− groups

Yaoguo Shen, Sangen Zhao and Junhua Luo

Coordination Chemistry Reviews, 2018, 366, 1
DOI: 10.1016/j.ccr.2018.03.012

Expanding the Chemistry of Salt-Inclusion Materials: Utilizing the Titanyl Ion as a Structure Directing Agent for the Targeted Synthesis of Salt-Inclusion Titanium Silicates

Gregory Morrison and Hans-Conrad zur Loye

Crystal Growth & Design, 2020, 20, 8071
DOI: 10.1021/acs.cgd.0c01317

Lead Mixed Oxyhalides Satisfying All Fundamental Requirements for High‐Performance Mid‐Infrared Nonlinear Optical Materials

Xinglong Chen, Hongil Jo and Kang Min Ok

Angewandte Chemie, 2020, 132, 7584
DOI: 10.1002/ange.202002291

Structure and photoluminescence properties of Ce3+ doped Ba7(BO3)3(SiO4)Br phosphors with complex anion groups

Xiangqiao Feng, Feiyan Long, Baoling Wang, Zhehui Weng, XiaoYan Wang, Yizhou Li and Haidong Ju

Inorganic Chemistry Communications, 2022, 137, 109180
DOI: 10.1016/j.inoche.2021.109180

LiBa2GaSi2O8: A Noncentrosymmetric Silicate Exhibiting Wide Transmission Range and Moderate Second Harmonic Generation Response

Mingyue Gu, Hu Liu, Xianchao Zhu, Zhanggui Hu, Jiyang Wang and Yicheng Wu

Inorg. Chem., 2025, 64, 25007
DOI: 10.1021/acs.inorgchem.5c05174

Confinement π‐Conjugated Moiety Tailoring to Achieve Record Deep‐UV Nonlinearity in Sulfates

Yujie Fan, Chengming Hu, Lingli Wu, Chensheng Lin, Chao Wang, Huixin Fan, Tao Yan and Min Luo

Angew Chem Int Ed, 2026, 65
DOI: 10.1002/anie.4703576

NaCa5BO3(SiO4)2 with Interesting Isolated [BO3] and [SiO4] Units in Alkali- and Alkaline-Earth-Metal Borosilicates

Zhaohong Miao, Yun Yang, Zhonglei Wei, Zhihua Yang, Sujuan Yu and Shilie Pan

Inorg. Chem., 2019, 58, 3937
DOI: 10.1021/acs.inorgchem.9b00002

An Overview on Recent Trends in Deep‐Ultraviolet (DUV) and Ultraviolet (UV) Nonlinear Optical Crystals

Anand Sekar, Usha Rani Muthurakku and Kalainathan Sivaperuman

ChemistrySelect, 2021, 6, 10688
DOI: 10.1002/slct.202101065

Lead Mixed Oxyhalides Satisfying All Fundamental Requirements for High‐Performance Mid‐Infrared Nonlinear Optical Materials

Xinglong Chen, Hongil Jo and Kang Min Ok

Angew Chem Int Ed, 2020, 59, 7514
DOI: 10.1002/anie.202002291

Understanding the Formation of Salt-Inclusion Phases: An Enhanced Flux Growth Method for the Targeted Synthesis of Salt-Inclusion Cesium Halide Uranyl Silicates

Gregory Morrison, Mark D. Smith and Hans-Conrad zur Loye

J. Am. Chem. Soc., 2016, 138, 7121
DOI: 10.1021/jacs.6b03205

Ba2ScBSi2O9: A Mixed-Coordination Borosilicate with a Low B/Si Ratio Exhibiting Enhanced Second Harmonic Generation Response

Ming Yang, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu and Hongping Wu

Inorg. Chem., 2024, 63, 16507
DOI: 10.1021/acs.inorgchem.4c02798

Deep Ultraviolet-Transparent Materials with Strong Second-Harmonic Response

Binqian Yuan, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu and Hongwei Yu

Chem. Mater., 2022, 34, 8004
DOI: 10.1021/acs.chemmater.2c01922

Second-order nonlinear optical crystals with mixed anions

Yu Pan, Sheng-Ping Guo, Bin-Wen Liu, Huai-Guo Xue and Guo-Cong Guo

Coordination Chemistry Reviews, 2018, 374, 464
DOI: 10.1016/j.ccr.2018.07.013

White‐Light Emission from a Semi‐Conductive Borate‐Stannate

Yuan Lin, Guan‐E Wang, Chun‐Li Hu, Jiang‐He Feng, Li‐Na Li and Jiang‐Gao Mao

Angewandte Chemie, 2019, 131, 13524
DOI: 10.1002/ange.201907650

Strong IR NLO Material Ba4MGa4Se10Cl2: Highly Improved Laser Damage Threshold via Dual Ion Substitution Synergy

Yan‐Yan Li, Peng‐Fei Liu, Lei Hu, Ling Chen, Hua Lin, Liu‐Jiang Zhou and Li‐Ming Wu

Advanced Optical Materials, 2015, 3, 957
DOI: 10.1002/adom.201500038

CRYSTAL CHEMISTRY OF NOVEL “ANTIZEOLITE” STRUCTURES

S. V. Rashchenko and T. B. Bekker

J Struct Chem, 2021, 62, 1935
DOI: 10.1134/S002247662112012X

A New Salt-Inclusion Single-Phased White Phosphor Ba₇B₃SiO₁₃Br:Dy³⁺ for White Light-Emitting Diodes

Hai Dong Ju, Bao Ling Wang and Qi Mei Yang

KEM, 2019, 803, 93
DOI: 10.4028/www.scientific.net/KEM.803.93

A new barium-containing alkali metal silicate fluoride NaBa3Si2O7F with deep-UV optical property

Zhaohong Miao, Yun Yang, Zhonglei Wei, Zhihua Yang, Tushagu Abudouwufu and Shilie Pan

Sci. China Mater., 2019, 62, 1454
DOI: 10.1007/s40843-019-9448-y

Cd8(BO3)4SiO4: Metal Cation Inducing the Formation of Isolated [BO3] and [SiO4] Units in Borate Silicate

Guangsheng Xu, Huimin Li, Jian Han, Xueling Hou, Zhihua Yang and Shilie Pan

Inorg. Chem., 2024, 63, 852
DOI: 10.1021/acs.inorgchem.3c03864

Learning From Nature: The Rational Non‐Centrosymmetric Structural Design in the Honeycomb‐Like Gaudefroyite Family

Fanlu Bu, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu and Hongwei Yu

Adv Funct Materials, 2025, 35
DOI: 10.1002/adfm.202414666

Ba3Zn4Si4O15: A Novel Centrosymmetric Silicate with Isolated SiO4 and Si2O7 Units

Aihaimaitijiang Ababaikeri, Gulimeikereyi Tuniyazi, Yanhui Zhang and Dilnur Malik

Zeitschrift anorg allge chemie, 2024, 650
DOI: 10.1002/zaac.202400026

Confinement π‐Conjugated Moiety Tailoring to Achieve Record Deep‐UV Nonlinearity in Sulfates

Yujie Fan, Chengming Hu, Lingli Wu, Chensheng Lin, Chao Wang, Huixin Fan, Tao Yan and Min Luo

Angewandte Chemie, 2026, 138
DOI: 10.1002/ange.4703576

Noncentrosymmetric Na2Ca4(CO3)5 Carbonate of “M13M23XY3Z” Structural Type and Affinity between Borate and Carbonate Structures for Design of New Optical Materials

Sergey V. Rashchenko, Vladimir V. Bakakin, Anton F. Shatskiy, Pavel N. Gavryushkin, Yurii V. Seryotkin and Konstantin D. Litasov

Crystal Growth & Design, 2017, 17, 6079
DOI: 10.1021/acs.cgd.7b01161

Deep Ultraviolet Nonlinear Optical Materials

T. Thao Tran, Hongwei Yu, James M. Rondinelli, Kenneth R. Poeppelmeier and P. Shiv Halasyamani

Chem. Mater., 2016, 28, 5238
DOI: 10.1021/acs.chemmater.6b02366

NaBa4(GaB4O9)2X3 (X = Cl, Br) with NLO-Active GaO4 Tetrahedral Unit: Experimental and ab Initio Studies

Ming Wen, Xin Su, Hongping Wu, Juanjuan Lu, Zhihua Yang and Shilie Pan

J. Phys. Chem. C, 2016, 120, 6190
DOI: 10.1021/acs.jpcc.6b00265

Hydrothermal Synthesis and Structural Investigation of a Crystalline Uranyl Borosilicate

Kristen A. Pace, Vladislav V. Klepov, Mark D. Smith, Travis Williams, Gregory Morrison, Jochen A. Lauterbach, Scott T. Misture and Hans-Conrad zur Loye

Inorganics, 2021, 9, 25
DOI: 10.3390/inorganics9040025

Recent Development of Non-π-Conjugated Deep Ultraviolet Nonlinear Optical Materials

Weiqi Huang, Sangen Zhao and Junhua Luo

Chem. Mater., 2022, 34, 5
DOI: 10.1021/acs.chemmater.1c02554

Rhodamine B Adsorptive Removal and Photocatalytic Degradation on MIL-53-Fe MOF/Magnetic Magnetite/Biochar Composites

Chanaka M. Navarathna, Narada B. Dewage, Akila G. Karunanayake, Erin L. Farmer, Felio Perez, El Barbary Hassan, Todd E. Mlsna and Charles U. Pittman

J Inorg Organomet Polym, 2020, 30, 214
DOI: 10.1007/s10904-019-01322-w

BaScSi2O6F: A barium-containing rare-earth metal silicate fluoride with a short cutoff edge

Xiya Wen, Tingwen Han, Yali Cao and Yun Yang

Journal of Molecular Structure, 2026, 1358, 145384
DOI: 10.1016/j.molstruc.2026.145384

Record‐Short Phase Matchability of Silicate: Charge‐Driven Lattice Distortion Enables Deep‐UV Phase Matching and Strong Optical Nonlinearity

Yi‐Gang Chen, Qin Chen, Mengke Zi, Xia Zhang, Yao Guo, Miriding Mutailipu, Xingxing Jiang, Zheshuai Lin and Xian‐Ming Zhang

Adv Funct Materials, 2026
DOI: 10.1002/adfm.74712

AeMg6Ga6S16 (Ae = Ca, Sr, Ba): The First Double Alkaline‐Earth Metal Chalcogenides with Excellent Performances

Jiale Chen, Yujie Zhang, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu and Hongwei Yu

Advanced Optical Materials, 2023, 11
DOI: 10.1002/adom.202202147

On a dual function of anions in crystallogenesis of compounds: Structure-directing and stabilizing

V. V. Bakakin

J Struct Chem, 2017, 58, 947
DOI: 10.1134/S0022476617050134

A Cubic Non-Centrosymmetric Mixed-Valence Iron Borophosphate–Phosphite

Hooman Yaghoobnejad Asl, Ronetta Morris, T. Thao Tran, P. Shiv Halasyamani, Kartik Ghosh and Amitava Choudhury

Crystal Growth & Design, 2016, 16, 1187
DOI: 10.1021/acs.cgd.5b01106

Synthesis, structure and luminescent properties of a new white phosphor Ba7(BO3)3(SiO4)Cl:Dy3+ for light-emitting diodes

Haidong Ju, Rui Qian, Xiujun Deng, Yanan Li, Baoling Wang and Zhehui Weng

Journal of Molecular Structure, 2018, 1173, 776
DOI: 10.1016/j.molstruc.2018.07.005

Recent advances in ultraviolet and deep-ultraviolet second-order nonlinear optical crystals

Chao Wu, Gang Yang, Mark G. Humphrey and Chi Zhang

Coordination Chemistry Reviews, 2018, 375, 459
DOI: 10.1016/j.ccr.2018.02.017

Recent development of metal borate halides: Crystal chemistry and application in second-order NLO materials

Ying Wang and Shilie Pan

Coordination Chemistry Reviews, 2016, 323, 15
DOI: 10.1016/j.ccr.2015.12.008