Issue 17, 2022

Recent advances in catalytic asymmetric [1,3]-rearrangement reactions

Abstract

Numerous elegant methodologies involving catalytic asymmetric [1,3]-rearrangement reactions have received increasing attention and gradually developed into significant synthetic tools in the past decades. These strategies provide novel ways for the synthesis of versatile organic building blocks and natural products. Hence, it is indispensable to succinctly present all such examples by means of disclosing the development of catalytic systems. This review mainly focuses on the recent breakthroughs involving catalytic asymmetric [1,3]-rearrangement processes in the last decade, which are sorted as transition metal catalysis, nucleophilic catalysis, Brønsted acid catalysis and Lewis acid catalysis. In addition, we present most of the reaction mechanisms and give insights to make the readers understand this exciting research field comprehensively and systematically.

Graphical abstract: Recent advances in catalytic asymmetric [1,3]-rearrangement reactions

Article information

Article type
Review Article
Submitted
28 Haz 2022
Accepted
13 Tem 2022
First published
27 Tem 2022

Org. Chem. Front., 2022,9, 4744-4756

Recent advances in catalytic asymmetric [1,3]-rearrangement reactions

Y. Zhang and Y. Chen, Org. Chem. Front., 2022, 9, 4744 DOI: 10.1039/D2QO01027E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements