Issue 25, 2021

Solid-state behaviors of imines: colossal biaxial positive thermal expansion, motion capability, and phase transitions

Abstract

Pedal motion or static disorder in single-component solids containing imine groups is demonstrated. Unique solid-state behaviors including colossal biaxial positive thermal expansion in one solid and a temperature-dependent phase transition in another are discussed. Imines exhibit torsional flexibility, which differs from the isoelectronic azo and olefin groups and influences solid-state behaviors.

Graphical abstract: Solid-state behaviors of imines: colossal biaxial positive thermal expansion, motion capability, and phase transitions

Supplementary files

Article information

Article type
Communication
Submitted
28 May 2021
Accepted
06 Haz 2021
First published
07 Haz 2021

CrystEngComm, 2021,23, 4439-4443

Author version available

Solid-state behaviors of imines: colossal biaxial positive thermal expansion, motion capability, and phase transitions

N. Juneja, E. Zahid, D. K. Unruh and K. M. Hutchins, CrystEngComm, 2021, 23, 4439 DOI: 10.1039/D1CE00706H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements