Issue 18, 2018

Visible-light photocatalytic trifluoromethylthiolation of aryldiazonium salts: conversion of amino group into trifluoromethylthiol group

Abstract

A visible-light photocatalytic trifluoromethylthiolation of aryl amine through in situ generation of aryldiazonium salts as key intermediates was achieved with S-trifluoromethyl 4-methoxylbenzenesulfonothioate for the first time. The mild reaction conditions and readily accessible reagents provide a practical protocol to prepare aryl trifluoromethylthioether.

Graphical abstract: Visible-light photocatalytic trifluoromethylthiolation of aryldiazonium salts: conversion of amino group into trifluoromethylthiol group

Supplementary files

Article information

Article type
Research Article
Submitted
18 Nis 2018
Accepted
26 May 2018
First published
28 May 2018

Org. Chem. Front., 2018,5, 2636-2640

Visible-light photocatalytic trifluoromethylthiolation of aryldiazonium salts: conversion of amino group into trifluoromethylthiol group

X. Zhao, X. Zheng, M. Tian, Y. Tong, B. Yang, X. Wei, D. Qiu and K. Lu, Org. Chem. Front., 2018, 5, 2636 DOI: 10.1039/C8QO00401C

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