Issue 9, 2023
From the journal:

Organic Chemistry Frontiers

Visible light mediated regioselective 1,3-oxylallylation of aryl cyclopropanes under redox-neutral conditions†

Ding-Xing Wang, ORCID logo a   Hui Wang,a   Yao Xu,a   Chi Zhang ORCID logo *a  and  Chao Feng ORCID logo *a  

* Corresponding authors

a Technical Institute of Fluorochemistry (TIF), Institute of Advanced Synthesis (IAS) State Key Laboratory of Material-Oriented Chemical Engineering, School of Chemistry and Molecular Engineering, Nanjing Tech University, 30 South Puzhu Road, Nanjing 211816, P. R. China
E-mail: 202110007083@njtech.edu.cn, iamcfeng@njtech.edu.cn

Abstract

A photoredox catalysed 1,3-oxylallylation of aryl cyclopropanes was accomplished by reaction with carboxylic acids and allyl sulfones. The redox-neutral reaction proceeded in a highly regioselective manner under mild conditions with good functional group compatibility. Simple operation and successful application to the late-stage functionalization of several natural product and pharmaceutical molecule related carboxylic acids add extra merits to the current protocol.

Graphical abstract: Visible light mediated regioselective 1,3-oxylallylation of aryl cyclopropanes under redox-neutral conditions

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/D3QO00281K
Article type
Research Article
Submitted
23 Şub 2023
Accepted
24 Mar 2023
First published
01 Nis 2023

Org. Chem. Front., 2023,10, 2147-2154

Permissions

Request permissions

Visible light mediated regioselective 1,3-oxylallylation of aryl cyclopropanes under redox-neutral conditions

D. Wang, H. Wang, Y. Xu, C. Zhang and C. Feng, Org. Chem. Front., 2023, 10, 2147 DOI: 10.1039/D3QO00281K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements