Aminosilanes have been broadly and sustainably prepared through the dehydrocoupling of amines and silanes with heterogeneous and homogeneous catalysts that span the periodic table.
Titanium complexes supported by tris(pyrazolyl)borate and alkoxide/aryloxide ligands catalyse N2 silylation.
A synthetic method that relies on a gold(I,I) complex and UVA LED light source to catalyse the α-alkynylation of tertiary α-silylamines by 1-iodoalkynes is described.
1,3-Diamine synthesis: a new radical addition/acyl migration cascade process was reported, giving access to 1,3-diamines via photocatalyzed reactions of enamides with α-aminoalkyl radicals.
Iron complexes with newly designed silyl-NHC bidentate ligands showed high performance in the catalytic double hydroboration of nitriles to produce N,N-bis(boryl)amines.