Pentafluorosulfanyl-functionalised BODIPY push–pull dyes for p-type dye-sensitized solar cells

Richard D. James, Linah S. Alqahtani, John Mallows, Heather V. Flint, Paul G. Waddell, Owen J. Woodford and Elizabeth A. Gibson

Sustainable Energy Fuels, 2023, 7, 1494
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In situ ortho-lithiation/functionalization of pentafluorosulfanyl arenes

Thanh V. Le and Olafs Daugulis

Chem. Commun., 2022, 58, 537
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Selective employment of electronic effects of the pentafluorosulfanyl group across linear and tripodal push–pull chromophores with two-photon absorption

Michaela Fecková, Milan Klikar, Chrisovalantou Vourdaki, Ioannis Georgoulis, Oldřich Pytela, Sylvain Achelle, Zdeňka Růžičková, Mihalis Fakis, Petr Beier and Filip Bureš

Mater. Adv., 2025, 6, 5713
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When SF5 outplays CF3: effects of pentafluorosulfanyl decorated scorpionates on copper

Anurag Noonikara-Poyil, Alvaro Muñoz-Castro, Andrii Boretskyi, Pavel K. Mykhailiuk and H. V. Rasika Dias

Chem. Sci., 2021, 12, 14618
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Synthesis, antioxidant and antitumoral activity of new 5′-arylchalcogenyl-3′-N-(E)-feruloyl-3′, 5′-dideoxy-amino-thymidine (AFAT) derivatives

Julliano G. Leal, Bruna Candia Piccoli, Cláudia Sirlene Oliveira, Fernanda D’Avila da Silva, Folorunsho Bright Omage, João Batista Teixeira da Rocha, Mariana Souza Sonego, Natália Vieira Segatto, Fabiana Kommling Seixas, Tiago Veiras Collares, Rafael Santos da Silva, Joelma Menegazzi Sarturi, Luciano Dornelles, Maria Amparo F. Faustino and Oscar E. D. Rodrigues

New J. Chem., 2022, 46, 22306
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Electron donor-acceptor (EDA)-complex enabled SF5Cl addition on alkenes and alkynes

Audrey Gilbert, Mélodie Birepinte and Jean-François Paquin

Journal of Fluorine Chemistry, 2021, 243, 109734
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Synthesis of pentafluorosulfanyl bicyclo[1.1.1]pentyl (hetero)aryl ketones

Xin Zhao, Jia-Yi Shou and Feng-Ling Qing

Sci. Sin.-Chim, 2025, 55, 1297
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Synthetic Access to Persulfuranyl Scaffolds via Direct and Indirect Methods

Yi Yang, Lulu Han, Liza Brettnacher, Louis Canavero and Anis Tlili

Chem. Rev., 2025, 125, 8426
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Pentafluorosulfanylation of Acrylamides: The Synthesis of SF5-Containing Isoquinolinediones with SF5Cl

Xinqiang Tan, Yuezhen Li, Ziyou Hao, Jia Wang, Xiangqian Liu, Bingqing Liu, Jianmei Yuan, Lizhen Fang, Ping-Xin Zhou and Yingling Wang

J. Org. Chem., 2024, 89, 15941
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Chemoselective Hydro(Chloro)pentafluorosulfanylation of Diazo Compounds with Pentafluorosulfanyl Chloride

Jia‐Yi Shou, Xiu‐Hua Xu and Feng‐Ling Qing

Angewandte Chemie, 2021, 133, 15399
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Ambiphilic Reactivity of SF5‐Alkynes Applied to Regioselective and Stereodivergent Halogenation Reactions: An Experimental and Theoretical Case Study

David Matchavariani, Lucas Popek, Jorge Juan Cabrera‐Trujillo, Thi Mo Nguyen, Nicolas Blanchard, Karinne Miqueu, Dominique Cahard and Vincent Bizet

Adv Synth Catal, 2024, 366, 3481
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Radical Addition of SF5Cl to Cyclopropenes: Synthesis of (Pentafluorosulfanyl)cyclopropanes

Gauthier Lefebvre, Olivier Charron, Janine Cossy and Christophe Meyer

Org. Lett., 2021, 23, 5491
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Research on Optimizing Material Structure Based on Optoelectronic Physical Performance System

Dinghan Ma

J. Phys.: Conf. Ser., 2021, 1802, 022105
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Development of retinoic acid receptor antagonists bearing trans-SF4-alkynyl structure as a linear linker

Shuichi Mori, Nozomi Tsuemoto, Emiko Kawachi, Chiharu Takubo, Aya Tanatani and Hiroyuki Kagechika

Tetrahedron, 2022, 123, 132967
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Strain-Release-Driven Synthesis of Pentafluorosulfanylated Four-Membered Rings under Energy Transfer Photocatalysis

Yi Yang, Lulu Han, Louis Canavero, Liza Brettnacher, Lhoussain Khrouz, Cyrille Monnereau, Maurice Médebielle and Anis Tlili

J. Am. Chem. Soc., 2025, 147, 27905
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Exploration toward the synthesis of aliphatic SF5-containing compounds using the Kolbe reaction

Vincent Mastalerz, Kevin Lam and Jean-François Paquin

Journal of Fluorine Chemistry, 2023, 268, 110113
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Chemoselective Csp2‐H Radical Alkylation of Aryl Diazonium Salts with 1‐Iodo‐3‐Pentafluorosulfanylbicyclo[1,1,1]pentane (SF5‐BCP‐I)†

Xin Zhao, Xin‐Yu Li, Jia‐Yi Shou and Feng‐Ling Qing

Chin. J. Chem., 2025, 43, 1523
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The radical reaction of ethynylbenziodoxolone (EBX) reagents with pentafluorosulfanyl chloride: New approach to SF5-substituted alkynes

Jia-Yi Shou, Xiu-Hua Xu and Feng-Ling Qing

Journal of Fluorine Chemistry, 2022, 261-262, 110018
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Exploration of 2-(pentafluoro-λ6-sulfanyl)ethane-1-sulfonyl chloride as a novel pentafluorosulfanylation reagent

Laurianne Verret, Kelly Burchell-Reyes, Jean-François Morin and Jean-François Paquin

Journal of Fluorine Chemistry, 2025, 282, 110387
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Synthesis of Substituted Pentafluorosulfanylpyrazoles Under Flow Conditions

Pascal Paquin, Nicolas DeGrâce, Guillaume Bélanger-Chabot and Jean-François Paquin

J. Org. Chem., 2024, 89, 3552
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(Hetero)aryl‐SVI Fluorides: Synthetic Development and Opportunities

Marc Magre, Shengyang Ni and Josep Cornella

Angew Chem Int Ed, 2022, 61
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Synthesis and application of pentafluorosulfanylation reagents and derived aliphatic SF5-containing building blocks

Günter Haufe

Tetrahedron, 2022, 109, 132656
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Synthesis of complex unnatural fluorine-containing amino acids

William D.G. Brittain, Carissa M. Lloyd and Steven L. Cobb

Journal of Fluorine Chemistry, 2020, 239, 109630
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Recent Advances in the Synthesis and Medicinal Chemistry of SF5 and SF4Cl Compounds

Monica Sani and Matteo Zanda

Synthesis, 2022, 54, 4184
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Regio‐ and Stereoselective Hydroelementation of SF5‐Alkynes and Further Functionalizations.

Lucas Popek, Jorge Juan Cabrera‐Trujillo, Vincent Debrauwer, Nicolas Blanchard, Karinne Miqueu and Vincent Bizet

Angew Chem Int Ed, 2023, 62
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Moving out of CF3‐Land: Synthesis, Receptor Affinity, and in silico Studies of NK1 Receptor Ligands Containing a Pentafluorosulfanyl (SF5) Group

Katarzyna Witoszka, Joanna Matalińska, Aleksandra Misicka and Piotr F. J. Lipiński

ChemMedChem, 2023, 18
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Chemistry of Pentafluorosulfanyl Derivatives and Related Analogs: From Synthesis to Applications

Reza Kordnezhadian, Bing‐Yu Li, Armir Zogu, Joachim Demaerel, Wim M. De Borggraeve and Ermal Ismalaj

Chemistry A European J, 2022, 28
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Chemoselective Hydro(Chloro)pentafluorosulfanylation of Diazo Compounds with Pentafluorosulfanyl Chloride

Jia‐Yi Shou, Xiu‐Hua Xu and Feng‐Ling Qing

Angew Chem Int Ed, 2021, 60, 15271
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(Hetero)aryl‐SVI Fluorides: Synthetic Development and Opportunities

Marc Magre, Shengyang Ni and Josep Cornella

Angewandte Chemie, 2022, 134
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A SF5 Derivative of Triphenylphosphine as an Electron-Poor Ligand Precursor for Rh and Ir Complexes

Maria Talavera, Silke Hinze, Thomas Braun, Reik Laubenstein and Roy Herrmann

Molecules, 2020, 25, 3977
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Pentafluorosulfanoxylation of Hypervalent Chlorines and Bromines for Access to Pentafluoro(biaryloxy)-λ6-sulfanes

Jia-Yi Shou and Feng-Ling Qing

Org. Lett., 2025, 27, 2815
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Photoinitiated anti‐Hydropentafluorosulfanylation of Terminal Alkynes

Mélodie Birepinte, Pier Alexandre Champagne and Jean‐François Paquin

Angew Chem Int Ed, 2022, 61
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Genetic Encoding of para-Pentafluorosulfanyl Phenylalanine: A Highly Hydrophobic and Strongly Electronegative Group for Stable Protein Interactions

Haocheng Qianzhu, Adarshi P. Welegedara, Holly Williamson, Amy E. McGrath, Mithun C. Mahawaththa, Nicholas E. Dixon, Gottfried Otting and Thomas Huber

J. Am. Chem. Soc., 2020, 142, 17277
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Aryl-, Akynyl-, and Alkenylbenziodoxoles: Synthesis and Synthetic Applications

Irina A. Mironova, Dmitrii M. Noskov, Akira Yoshimura, Mekhman S. Yusubov and Viktor V. Zhdankin

Molecules, 2023, 28, 2136
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On the experimental measurement of barriers to four-fold internal rotation in pentafluorosulfanyl-containing compounds: The microwave spectra of C3H5-SF5 and C4H7-SF5

W. Orellana, Susanna L. Stephens, Stewart E. Novick and S.A. Cooke

Journal of Molecular Spectroscopy, 2020, 371, 111300
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Synthesis and biological evaluation of benzodiazepines containing a pentafluorosulfanyl group

Arathy Jose, Raysa Khan Tareque, Martin Mortensen, Remi Legay, Simon J. Coles, Graham J. Tizzard, Barnaby W. Greenland, Trevor G. Smart, Mark C. Bagley and John Spencer

Tetrahedron, 2021, 85, 132020
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Oxidative Fluorination of Selenium and Tellurium Compounds using a Thermally Stable Phosphonium SF5−Salt Accessible from SF6

Tobias Eder, Florenz Buß, Lukas F. B. Wilm, Michael Seidl, Maren Podewitz and Fabian Dielmann

Angew Chem Int Ed, 2022, 61
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Light-activation of SF5Cl for the atom transfer radical addition onto alkenes and alkynes

Marie-Rose Ouellet-Du Berger, Maxim Boucher and Jean-François Paquin

Journal of Fluorine Chemistry, 2023, 268, 110131
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Synthesis of N-(2-SF5-ethyl)amines and impact of the SF5 substituent on their basicity and lipophilicity

Audrey Gilbert, Pauline Langowski and Jean-François Paquin

Tetrahedron, 2021, 98, 132424
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Photo-induced hydroxypentafluorosulfanylation of alkenes with SF5Cl and oxygen gas and their further derivatization

Yuanyang Jiang, Xiaoli Meng, Jiangshan Zhang, Gang Wu, Xinjing Lin and Shuo Guo

Nat Commun, 2024, 15
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Oxidative Fluorination of Selenium and Tellurium Compounds using a Thermally Stable Phosphonium SF5−Salt Accessible from SF6

Tobias Eder, Florenz Buß, Lukas F. B. Wilm, Michael Seidl, Maren Podewitz and Fabian Dielmann

Angewandte Chemie, 2022, 134
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Synthesis and Physicochemical Properties of 2-SF5-(Aza)Indoles, a New Family of SF5 Heterocycles

Vincent Debrauwer, Ivo Leito, Märt Lõkov, Sofja Tshepelevitsh, Michael Parmentier, Nicolas Blanchard and Vincent Bizet

ACS Org. Inorg. Au, 2021, 1, 43
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Synthesis and Reaction of Pentafluorosulfanyl Chloride (SF5Cl)

Jia‐Yi Shou and Feng‐Ling Qing

Chin. J. Chem., 2025
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A Polyfluoroalkyl‐Containing Non‐fullerene Acceptor Enables Self‐Stratification in Organic Solar Cells

Shihao Chen, Ling Hong, Minghao Dong, Wanyuan Deng, Lin Shao, Yuanqing Bai, Kai Zhang, Chunchen Liu, Hongbin Wu and Fei Huang

Angewandte Chemie, 2023, 135
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Exploration towards the bromopentafluorosulfanylation reaction of terminal alkynes

Marie-Rose Ouellet-Du Berger, Jean-Philippe Bouillon and Jean-François Paquin

Journal of Fluorine Chemistry, 2025, 282, 110386
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Photoinitiated anti‐Hydropentafluorosulfanylation of Terminal Alkynes

Mélodie Birepinte, Pier Alexandre Champagne and Jean‐François Paquin

Angewandte Chemie, 2022, 134
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Expanding the Repertoire of Low‐Molecular‐Weight Pentafluorosulfanyl‐Substituted Scaffolds

Arathy Jose, Daniel Guest, Remi LeGay, Graham J. Tizzard, Simon J. Coles, Mariliza Derveni, Edward Wright, Lester Marrison, Alpha A. Lee, Aaron Morris, Matt Robinson, Frank von Delft, Daren Fearon, Lizbé Koekemoer, Tetiana Matviuk, Anthony Aimon, Christopher J. Schofield, Tika R. Malla, Nir London, Barnaby W. Greenland, Mark C. Bagley, John Spencer and The Covid Moonshot Consortium

ChemMedChem, 2022, 17
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Radical 1,3-Difunctionalization of β,γ-Unsaturated Ketones via Concomitant 1,2-Carbonyl Migration: An Entrance to β-SF5-/β-CF3SF4 Ketones

Jia-Yu Li, Ying Liu, Donglei Sun, Gang Wu, Shuai-Shuai Yue, Hui-Yi Yang, Hao Zhang, Wei Zhang, Meng-Meng Zheng, Xiao-Song Xue and Shuo Guo

J. Am. Chem. Soc., 2025, 147, 26124
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Polymer electrets for organic nonvolatile memory devices: Recent advances

Yi Jie Eng, Yi-Hsun Weng, Algin Biying Oh, Cheng-Liang Liu and Julian M.W. Chan

Materials Today Chemistry, 2024, 42, 102380
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A Polyfluoroalkyl‐Containing Non‐fullerene Acceptor Enables Self‐Stratification in Organic Solar Cells

Shihao Chen, Ling Hong, Minghao Dong, Wanyuan Deng, Lin Shao, Yuanqing Bai, Kai Zhang, Chunchen Liu, Hongbin Wu and Fei Huang

Angew Chem Int Ed, 2023, 62
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Amine–borane complex-initiated SF5Cl radical addition on alkenes and alkynes

Audrey Gilbert, Pauline Langowski, Marine Delgado, Laurent Chabaud, Mathieu Pucheault and Jean-François Paquin

Beilstein J. Org. Chem., 2020, 16, 3069
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Reactions of difluoro-pentafluorosulfanyl-iodomethane (SF5CF2I) with electronically different types of alkenes

Piotr Dudziński, Andrej V. Matsnev, Joseph S. Thrasher and Günter Haufe

Journal of Fluorine Chemistry, 2022, 264, 110051
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Regio‐ and Stereoselective Hydroelementation of SF5‐Alkynes and Further Functionalizations.

Lucas Popek, Jorge Juan Cabrera‐Trujillo, Vincent Debrauwer, Nicolas Blanchard, Karinne Miqueu and Vincent Bizet

Angewandte Chemie, 2023, 135
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