Issue 36, 2018

The hetero-cubane structures of the heavy alkali metal tert-amyloxides [MOCMe2Et]4 (M = K, Rb, Cs)

Abstract

A series of alkali metal (Li–Cs) alkoxides of tert-pentanol (1,1-dimethylpropan-1-ol) have been prepared by reaction of the corresponding metal with the alcohol in n-hexane or n-heptane. The compounds were purified by vacuum sublimation and crystallised in n-hexane to produce crystals suitable for single-crystal X-ray diffraction studies. The structures of the potassium, rubidium, and caesium compounds revealed tetrameric units with additional intra- and intermolecular interactions between the metal atom and alkoxide methyl groups, increasing with the size of the metal involved.

Graphical abstract: The hetero-cubane structures of the heavy alkali metal tert-amyloxides [MOCMe2Et]4 (M = K, Rb, Cs)

Supplementary files

Article information

Article type
Paper
Submitted
18 เม.ย. 2561
Accepted
30 พ.ค. 2561
First published
31 พ.ค. 2561

Dalton Trans., 2018,47, 12582-12586

The hetero-cubane structures of the heavy alkali metal tert-amyloxides [MOCMe2Et]4 (M = K, Rb, Cs)

M. Kaiser and J. Klett, Dalton Trans., 2018, 47, 12582 DOI: 10.1039/C8DT01545G

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