Issue 62, 2024

Construction of a redox-active metal–organic framework with an octanuclear lithium one-dimensional building block

Abstract

A stable lithium metal–organic framework, constructed using a redox-active N,N,N′,N′-tetrakis(4-carboxyphenyl)-1,4-phenylenediamine linker and Li8 cluster-based one-dimensional rod secondary building unit, exhibits good stability and reversible redox activity. The Li8-MOF, which can be oxidized by AgNO3, has the potential to function as an electrochromic device, thereby advancing the development of smart MOF materials.

Graphical abstract: Construction of a redox-active metal–organic framework with an octanuclear lithium one-dimensional building block

Supplementary files

Article information

Article type
Communication
Submitted
01 พ.ค. 2567
Accepted
27 มิ.ย. 2567
First published
03 ก.ค. 2567

Chem. Commun., 2024,60, 8047-8050

Construction of a redox-active metal–organic framework with an octanuclear lithium one-dimensional building block

S. Li, Y. Meng, M. Xu, G. Zhang and J. Su, Chem. Commun., 2024, 60, 8047 DOI: 10.1039/D4CC02111H

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