Issue 75, 2023

Phosphorescence enhancement of pyridinium macrocycles by poly(vinylalcohol)

Abstract

A phosphorescence enhancement of pyridinium macrocycle/monomer phosphors is realized with up to 14.7-fold prolonging of the phosphorescence lifetimes and visible afterglow by doping into a poly(vinylalcohol) (PVA) matrix. The abundant hydrogen-bonding interactions and electrostatic interactions between the phosphors and the PVA suppressed the nonradiative decay processes, slowed down the radiative decay and nonradiative decay of triplet states, and therefore promoted the long-lived RTP.

Graphical abstract: Phosphorescence enhancement of pyridinium macrocycles by poly(vinylalcohol)

Supplementary files

Article information

Article type
Communication
Submitted
04 ก.ค. 2566
Accepted
24 ส.ค. 2566
First published
24 ส.ค. 2566

Chem. Commun., 2023,59, 11248-11251

Phosphorescence enhancement of pyridinium macrocycles by poly(vinylalcohol)

Z. Zhang, C. Deng, C. Shen, R. Xu, X. Wang, Y. Wang, B. Ding, B. Li, J. Li and C. Li, Chem. Commun., 2023, 59, 11248 DOI: 10.1039/D3CC03225F

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