Issue 63, 2022

Functional supramolecular gels based on poly(benzyl ether) dendrons and dendrimers

Abstract

Supramolecular gels, as a fascinating and useful class of soft materials, constructed from low-molecular-weight gelators via noncovalent interactions have attracted increasing attention in the past few decades. Dendrimers and dendrons are highly branched and monodisperse macromolecules with a well-defined three-dimensional architecture and multiple surface functionalities. In recent years, poly(benzyl ether) dendrimers and dendrons are found to be powerful candidates for constructing gel phase materials in organic or aqueous media due to the advantages of capability of forming multiple noncovalent interactions and significant steric impact. In this Feature Article, we provide a comprehensive overview of recent progress in supramolecular gels involving poly(benzyl ether) dendritic molecules. Firstly, we outline the molecular design strategies of dendritic gelators with an emphasis on the discussion of their gelating units and position in molecular structures. Subsequently, we discuss the potential applications of dendritic gels in light harvesting, stimuli responsive materials, sensors and environmental remediation. In addition, the potential challenges and future perspectives of poly(benzyl ether) dendritic gels have also been discussed. It is hoped that this feature article will attract increasing attention and provide some valuable insights for the future design and evolution of supramolecular gels.

Graphical abstract: Functional supramolecular gels based on poly(benzyl ether) dendrons and dendrimers

Article information

Article type
Feature Article
Submitted
29 พ.ค. 2565
Accepted
06 ก.ค. 2565
First published
06 ก.ค. 2565

Chem. Commun., 2022,58, 8736-8753

Functional supramolecular gels based on poly(benzyl ether) dendrons and dendrimers

Y. Feng, Z. Liu, H. Chen and Q. Fan, Chem. Commun., 2022, 58, 8736 DOI: 10.1039/D2CC03040C

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