Issue 79, 2021

Tris-NHC-propagated self-supported polymer-based Pd catalysts for heterogeneous C–H functionalization

Abstract

Three-dimensionally propagated imidazolium-containing mesoporous coordination polymer and organic polymer-based platforms were successfully exploited to develop single-site heterogenized Pd–NHC catalysts for oxidative arene/heteroarene C–H functionalization reactions. The catalysts were efficient in directed arene halogenation, and nondirected arene and heteroarene arylation reactions. High catalytic activity, excellent heterogeneity and recyclability were offered by these systems making them promising candidates in the area of heterogeneous C–H functionalization, where efficient catalysts are still scarce.

Graphical abstract: Tris-NHC-propagated self-supported polymer-based Pd catalysts for heterogeneous C–H functionalization

Supplementary files

Article information

Article type
Communication
Submitted
11 ส.ค. 2564
Accepted
08 ก.ย. 2564
First published
08 ก.ย. 2564

Chem. Commun., 2021,57, 10182-10185

Tris-NHC-propagated self-supported polymer-based Pd catalysts for heterogeneous C–H functionalization

T. Mandal, T. K. Dutta, S. Mohanty and J. Choudhury, Chem. Commun., 2021, 57, 10182 DOI: 10.1039/D1CC04429J

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